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Merck
CN

908193

3CzClIPN

powder or crystals

别名:

2,4,6-Tri(9H-carbazol-9-yl)-5-chloroisophthalonitrile

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关于此项目

经验公式（希尔记法）:
C44H24ClN5
化学文摘社编号:
1469704-61-7
分子量:
658.15
MDL number:
MFCD32062494
UNSPSC Code:
12352101
NACRES:
NA.22

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产品名称

3CzClIPN,

SMILES string

Clc1c(c(c(c(c1[n]8c9c(c%10c8cccc%10)cccc9)C#N)[n]5c6c(c7c5cccc7)cccc6)C#N)[n]2c3c(c4c2cccc4)cccc3

InChI

1S/C44H24ClN5/c45-41-43(49-37-21-9-3-15-29(37)30-16-4-10-22-38(30)49)33(25-46)42(48-35-19-7-1-13-27(35)28-14-2-8-20-36(28)48)34(26-47)44(41)50-39-23-11-5-17-31(39)32-18-6-12-24-40(32)50/h1-24H

InChI key

AETFKBFYWGEUOV-UHFFFAOYSA-N

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

相关类别

Application

3CzClIPN is cyanoarene-based donor-acceptor photocatalyst developed by the Zeitler group. While this catalyst has a balanced redox profile, allowing for its use in a variety of transformations, it stands out as the most oxidizing catalyst of the family.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A Toolbox Approach To Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry: Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor-Acceptor Cyanoarenes

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number
MKCS2407

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Elisabeth Speckmeier et al.
Journal of the American Chemical Society, 140(45), 15353-15365 (2018-10-03)
The targeted choice of specific photocatalysts has been shown to play a critical role for the successful realization of challenging photoredox catalytic transformations. Herein, we demonstrate the successful implementation of a rational design strategy for a series of deliberate structural

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