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Merck
CN

914770

Diethyl-4-((3r,5r,7r)-adamantan-1-yl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate

≥95%

别名:

4-Alkyl-1,4-dihydropyridine reagent, DHP reagent for light-mediated His modification

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经验公式（希尔记法）:
C23H33NO4
化学文摘社编号:
2395845-84-6
分子量:
387.51
UNSPSC Code:
12352200
Assay:
≥95%
Form:
powder

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assay

≥95%

form

powder

storage temp.

−20°C

Application

Diethyl-4-((3r,5r,7r)-adamantan-1-yl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate was reported to chemoselectively modify histidine under visible light where the unsubstituted nitrogen groups on the modified His imidazole are conserved.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Histidine-specific peptide modification via visible-light-promoted C-H alkylation

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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Xiaoping Chen et al.
Journal of the American Chemical Society, 141(45), 18230-18237 (2019-10-23)
Histidine (His) carries a unique heteroaromatic imidazole side chain and plays irreplaceable functional roles in peptides and proteins. Existing strategies for site-selective histidine modification predominantly rely on the N-substitution reactions of the moderately nucleophilic imidazole group, which inherently suffers from

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