乙酰丙酮钯 (II)

Name: 乙酰丙酮钯 (II)
Brand: ALDRICH

≥99.9% trace metals basis

别名:

2,4-戊二酸钯(II), Pd(acac)₂

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About This Item

线性分子式:

Pd(C₅H₇O₂)₂

CAS Number:

14024-61-4

分子量:

304.64

Beilstein:

4136188

MDL编号:

MFCD00000025

UNSPSC代码:

12161600

NACRES:

NA.23

质量水平

200

方案

≥99.9% trace metals basis

反应适用性

core: palladium

mp

200-251 °C (dec.)

应用

PEM fuel cells
homogeneous catalyst
material synthesis precursor

SMILES字符串

CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

JKDRQYIYVJVOPF-FDGPNNRMSA-L

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应用

钯催化交叉偶联反应应用指南

Palladium(II) 2,4-pentanedionate can be used to synthesize palladium(II) complexes applicable in common cross-coupling reactions like Suzuki, Heck and Buchwald-Hartwig coupling. As a palladium precursor, it can be used to synthesize hollow Pd/Pt single-crystalline nanocubes with enhanced electrocatalytic activity due to increased surface area. The surface modification of TiO₂ using Pd(acac)₂ as a metal-organic precursor has enhanced its photocatalytic activity under UV irradiation. Pd(acac)₂ can also be used to develop bimetallic alloy NP catalysts applicable in formic acid dehydrogenation.