表单
powder
应用
peptide synthesis
应用
Catalyst employed for the enantioselective epoxidation of enones to epoxy ketones (Juliá-Colonna epoxidation) in heterogeneous phase. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline's reagent guide.
Novel conditions for the Juliá–Colonna epoxidation reaction providing efficient access to chiral, nonracemic epoxides
Novel conditions for the Juliá–Colonna epoxidation reaction providing efficient access to chiral, nonracemic epoxides
其他说明
用于非均相条件下催化烯酮的对映选择性环氧化反应,生成环氧酮(Juliá-Colonna 环氧化反应)
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
R W Flood et al.
Organic letters, 3(5), 683-686 (2001-03-22)
[reaction: see text]. Polyethylene glycol (PEG)-bound poly-L-leucine acts as a THF-soluble catalyst for the Juliá-Colonna asymmetric epoxidation of enones. Excellent enantioselectivities may be obtained even with short chain length polyleucine. FT-IR investigations have determined that the catalytically active polyleucine components
C. Lauret
Tetrahedron Asymmetry, 12, 2359-2359 (2001)
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