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Merck
CN

931985

酞青

别名:

Dehydrophthalocyanine, H2Pc, Pigment Blue 16

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关于此项目

经验公式(希尔记法):
C32H18N8
化学文摘社编号:
分子量:
514.54
UNSPSC Code:
12352103
NACRES:
NA.23
Beilstein/REAXYS Number:
378323
MDL number:
Solubility:
DMF: soluble
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InChI

1S/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40)

InChI key

IEQIEDJGQAUEQZ-UHFFFAOYSA-N

SMILES string

c1ccc2c3nc(nc4[nH]c(nc5nc(nc6[nH]c(n3)c7ccccc67)c8ccccc58)c9ccccc49)c2c1

description

Hole Transport Layer
PL: 418 nm
μh ≈ 4.0 x 10−5 cm2 V−1 s−1

mp

>300 °C (dec.)

transition temp

Tg >350 °C ((0.5% weight loss))

solubility

DMF: soluble

orbital energy

HOMO 5.35 eV 
LUMO 3.35 eV 

UV absorption

λ: 279 nm Amax
λ: 693 nm Amax

Quality Level

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Application

Phthalocyanine is a versatile functional dye with a range of intriguing properties enabling them to find practical applications in various disciplines from organic electronics, energy harvesting and biomedicine. Its derivatives exhibit semiconducting properties, making them valuable materials in organic electronics. They can be incorporated as active layers in organic photovoltaic cells, organic field-effect transistors (OFETs), organic light-emitting diodes (OLEDs), and other organic electronic devices.
Phthalocyanine, also known as H2Pc, is a versatile functional dye with a range of intriguing properties enabling them to find practical applications in various disciplines from organic electronics, energy harvesting and biomedicine.
In the field of organic electronics, H2Pc has been explored as a popular Hole Injection Layer (HIL) material for organic light-emitting diode devices (OLEDs).This special compound has also been explored for solar cells application given its robust and intensely colored macrocycles (blue pigments) with high chem., thermal and light stability, properties that are of paramount importance for realistic photovoltaic applications. H2Pc have attracted special attention as photosensitizers for dye-sensitized solar cells (DSSCs).
In biomedicine, phthalocyanine can serve as selective fluorescent probes for bioanal. and bioimaging, and as efficient photosensitizers for photodynamic therapy of cancer and other non-cancerous conditions.

存储类别

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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The unique features and promises of phthalocyanines as advanced photosensitisers for photodynamic therapy of cancer
Lo, Pui-Chi, et al.
Chemical Society Reviews, 49, 1041-1056 (2020)
Turning Photons into Drugs: Phthalocyanine-Based Photosensitizers as Efficient Photoantimicrobials
Galstyan, A.
Chemistry?A European Journal , 27, 1903-1920 (2021)
Spin-triplet-mediated up-conversion and crossover behavior in single-molecule electroluminescence
Chen, Gong, et al.
Physical Review Letters, 122, 177401-177401 (2019)
Electronic properties of CuPc and H2Pc: an experimental and theoretical study
Nardi, Marco Vittorio, et al
Physical Chemistry Chemical Physics, 15, 12864-12881 (2013)
Phthalocyanines for dye-sensitized solar cells
Urbani, M. et al.
Coordination Chemistry Reviews, 381, 1-64 (2019)

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