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Merck
CN

935530

氯化银

-325 mesh, 99.99% trace metals basis (excluding Na)

别名:

Silver chloride, Chlorosilver, Silver monochloride

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关于此项目

经验公式(希尔记法):
AgCl
化学文摘社编号:
分子量:
143.32
UNSPSC Code:
12352302
MDL number:
NACRES:
NA.21
Assay:
73.4-77.1% (with AgNO3, titration), 99.99% trace metals basis (excluding Na)
Form:
powder
Solubility:
water: soluble
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InChI key

HKZLPVFGJNLROG-UHFFFAOYSA-M

InChI

1S/Ag.ClH/h;1H/q+1;/p-1

SMILES string

Cl[Ag]

vapor pressure

1 mmHg ( 912 °C)

assay

73.4-77.1% (with AgNO3, titration), 99.99% trace metals basis (excluding Na)

form

powder

reaction suitability

core: silver

impurities

≤150 ppm (trace metals analysis)

color

white to off-white

particle size

-325 mesh

mp

455 °C (lit.), 455 °C

solubility

water: soluble

Quality Level

General description

Silver(I) chloride is a off-white solid which is slightly soluble in water. Silver(I) chloride turns black in the presence of heat, indicating the formation of silver.
It can be produced easily through the combination of silver nitrate, sodium chloride, or cobalt(II) chloride.

Application

Silver chloride (AgCl) is widely employed as a catalyst, photographic material, and ionic semiconductor material.


Silver chloride (AgCl) can be used for a variety of applications such as: the coating on the silver wire that can be used as a reference electrode in electrochemistry


It can be deposited on conducting material for stable photocatalysis under visible light .


In addition, Silver(I)chloride is used to synthesis polymeric silver(I) complexes with 1D and 3D network .


Moreover, Silver(I)chloride is also used as a catalyst in the preparation of 1,2,3-triazoles from alkynes and azides.

pictograms

CorrosionEnvironment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1

flash_point_f

Not applicable

flash_point_c

Not applicable

存储类别

11 - Combustible Solids

法规信息

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分析证书(COA)

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Sensitivities of key parameters in the preparation of silver/silver chloride electrodes used in Harned cell measurements of pH
Paul J, et al.
Sensors (Basel, Switzerland), 11(8), 8072-8084 (2011)
Controlled Assembly Based on Multibridging Thiolate Ligands: New Polymeric Silver(I) Complexes with One-Dimensional Chain and Three-Dimensional Network Structures.
Hong M, et al.
Inorganic Chemistry, 38(3), 600-602 (1999)
Ag@ AgCl: a highly efficient and stable photocatalyst active under visible light.
Wang P, et al.
Angewandte Chemie (International Edition in English), 47(41), 7931-7933 (2008)
The silver chloride photoanode in photoelectrochemical water splitting
Schurch D, et al.
The Journal of Physical Chemistry B, 106(49), 12764-12775 (2002)
Paul J Brewer et al.
Sensors (Basel, Switzerland), 11(8), 8072-8084 (2011-12-14)
A questionnaire was completed by fourteen world leading national metrology institutes to study the influence of several variables in the preparation of Ag/AgCl electrodes on the accuracy of Harned cell measurements of pH. The performance of each institute in the

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