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Merck
CN

935611

碳酸乙烯亚乙酯

greener alternative

≥99.9%, anhydrous, battery grade

别名:

4-乙烯基-1,3-二氧戊环-2-酮, VEC

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关于此项目

经验公式(希尔记法):
C5H6O3
化学文摘社编号:
分子量:
114.10
UNSPSC Code:
12352005
MDL number:
NACRES:
NA.21
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form

liquid

InChI key

BJWMSGRKJIOCNR-UHFFFAOYSA-N

InChI

1S/C5H6O3/c1-2-4-3-7-5(6)8-4/h2,4H,1,3H2

SMILES string

C=CC1COC(=O)O1

grade

battery grade

description

Application: Battery manufacturing

assay

≥99.9%

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤100 ppm H2O

refractive index

n20/D 1.45 (lit.)

bp

237 °C/733 mmHg (lit.)

density

1.188 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

storage temp.

2-8°C

Quality Level

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General description

4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic organic compound with the molecular formula C5H6O3. It is a clear, colorless liquid with a high boiling point and is miscible with carbonate and ether solvents used in lithium-ion batteries (LIBs). Our battery grade VEC is differentiated by its high purity and low trace moisture to help ensure consistent performance in battery applications.
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Application

Anhydrous, battery grade 4-vinyl-1,3-dioxolan-2-one (VEC) is commonly used as an electrolyte additive in lithium-ion batteries (LIBs) to improve battery performance. VEC helps to form a stable film on the anode surface called a solid electrolyte interface (SEI). The SEI acts as a barrier that prevents further reaction between the electrolyte and the anode and thereby enhances the cyclic stability of the battery. For example, the addition of 2 wt.% VEC to the electrolyte formulation enhanced cycling performance in experiments both with Li metal anodes and graphite anodes In the electrolyte formulation, often VEC is added to be 2-10 wt.% of the solvent blend; however, scientists have even used VEC as the sole solvent in a lithium-metal battery with great results including long cycle life over 1000 cycles and reduced flammability

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

206.4 °F - closed cup

flash_point_c

96.9 °C - closed cup


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Vinyl ethylene carbonate as an electrolyte additive for high-voltage LiNi0.4Mn0.4Co0.2O2/graphite Li-ion batteries
Zuo X, et al.
Ionics, 22, 201-208 (2016)
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes
Yang Y, et al.
ACS Applied Materials & Interfaces, 11, 6118-6125 (2019)
Highly safe and cyclable Li-metal batteries with vinylethylene carbonate electrolyte
Zhang Q, et al.
Nano Energy, 74, 104860-104860 (2020)

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