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Merck
CN

939900

NaFSI electrolyte powder

greener alternative

anhydrous, battery grade, 99.9% trace metals basis

别名:

Sodium Bis(fluorosulfonyl)imide, Imidodisulfuryl fluoride sodium salt, Sodium bis(fluorosulfonyl)imide

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关于此项目

经验公式(希尔记法):
F2NO4S2Na
化学文摘社编号:
分子量:
203.12
UNSPSC Code:
12352107
NACRES:
NA.21
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SMILES string

[N-](S(=O)(=O)F)S(=O)(=O)F.[Na+]

grade

battery grade

assay

99.9% trace metals basis

form

powder

mol wt

203.3 g/mol

Quality Level

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

109 °C

solubility

0.1 M carbonate: soluble (lit.), soluble (ethers: soluble(lit.)), soluble (glymes: soluble(lit.)), water: very soluble (lit.)

density

2.4 g/cm3

application(s)

battery manufacturing

greener alternative category

General description

Sodium bis(fluorosulfonyl)imide, abbreviated NaFSI, is a white, crystalline salt. It is hygroscopic and deliquescent and usually stored under inert atmosphere. NaFSI is soluble in water, carbonates (including dimethyl carbonate, diethyl carbonate, and propylene carbonate), glymes (including monoglyme, diglyme, and triglyme), dimethoxyethane, trimethyl phosphate, and bis(fluorosulfonyl)imide-based ionic liquids such as N-methyl-N-propylpyrrolidinium bis(fluorosulfonyl)imide ([C3mpyr]+FSI-) or N-butyl-N-methylpyrrolidinium ([C4mpyr]+FSI-). NaFSI melts at 109 °C.
NAFSI Electrolyte Powder is a high-purity sodium salt that enhances battery stability, safety, and lifespan. Its compatibility with various chemistries and role in forming stable interfaces support efficient, durable, and greener energy storage solutions. Click here for more information.

Application

NaFSI is commonly used as an electrolytic salt in sodium-ion batteries because of its high solubility and high ionic conductivity in solution. Our battery grade NaFSI with low moisture, acid, and high purity is tailored to sodium-ion battery applications. NaFSI is compatible with a host of cathode materials including Na2Ti3O7 , Na3V2(PO4)3 , and anode materials such as hard carbon and sodium metal. Recently, scientists have found that high-concentration and localized high-concentration electrolytes using NaFSI outperform traditional dilute electrolytes, enabling dramatically improved cycling stability. , These localized high-concentration electrolytes typically involve 1.5 M NaFSI in a carbonate or ether solvent that is diluted with a fluoroether. Another recent report showed that electrolytes composed of high-concentration NaFSI in ionic liquids form favorable solid electrolyte interphase and enable stable cycling with sodium metal anodes for over 700 cycles.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes
Zheng J,et.al
American Chemical Science Journal, 3, 315?321 -315?321 (2018)
Highly Reversible Sodium Ion Batteries Enabled by Stable Electrolyte-Electrode Interphases
Jin Y,et.al
American Chemical Science Journal, 5, 3212?3220-3212?3220 (2020)
Engineering high-energy-density sodium battery anodes for improved cycling with superconcentrated ionic-liquid electrolytes
Rakov D A,et.al
Nature Materials, 19, 1096-1101 (2020)
Sodium Storage and Transport Properties in Layered Na2Ti3O7 for Room-Temperature Sodium-Ion Batteries
Pan H,et.al
Advanced Energy Materials, 3, 1186?1194 -1186?1194 (2013)
Ultraconcentrated Sodium Bis(fluorosulfonyl)imide-Based Electrolytes for High-Performance Sodium Metal Batteries
Lee J,et.al
American Chemical Science Journal, 9, 3723?3732-3723?3732 (2017)

商品

Discover the role of electrolytes in sodium-ion batteries, to enhance performance, safety, and sustainability in energy storage solutions.

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