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Merck
CN

941964

Lithium manganese iron phosphate

LiMn0.7Fe0.3PO4, Cathode active material, powder

别名:

Iron lithium manganese phosphate, LFMP, LMFP

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UNSPSC Code:
26111700
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assay

99.9%

form

powder

mol wt

157.12 g/mol

composition

LiMn0.7Fe0.3PO4

Quality Level

particle size

<150 μm

capacity

(First cycle discharge capacity: 140-150 mAh/g at 0.1C (typical))

density

3.5 g/cm3 ((crystal density lit.))

application(s)

battery manufacturing

General description

LiMn0.7Fe0.3PO4, commonly referred to as LMFP or LMFP 70/30, is an advanced cathode material that merges the structural stability of lithium iron phosphate, LiFePO4 or LFP, with the enhanced energy density characteristics of lithium manganese phosphate, LiMnPO4. This olivine-structured compound features a unique blend of iron and manganese, enabling it to achieve a nominal voltage of approximately 3.8V versus lithium, compared to the 3.4V of traditional LFP. The LMFP material provides a specific capacity of about 140-150 mAh/g, which is slightly lower than that of LFP, but its higher voltage results in comparable energy density. This LMFP 70/30 is a crystalline powder that has been sieved through a 100 mesh to achieve a particle size of less than 150 µm. It is suitable for various research applications where the intrinsic properties of the cathode material are of primary interest.

Application

Our LiFe0.3Mn0.7PO4 is ideally suited for research and development of high-performance lithium-ion batteries, particularly in applications that demand enhanced safety and energy density. With a higher nominal voltage of 3.8V, LMFP serves as an excellent candidate for replacing nickel-cobalt-based cathodes, providing a cost-effective, cobalt-free alternative. The robust olivine structure and superior thermal stability of LMFP ensure safe operation across a wide range of temperatures, making it an ideal material for electric vehicles and energy storage systems. While our LMFP 70/30 provides an excellent starting point for research, it is not optimized for fast-charging applications. For improved performance in fast-charging scenarios, we recommend jet-milling the material to achieve a smaller particle size, such as 1 µm, and applying a carbon coating to the milled material. This approach can enhance the electrochemical performance and facilitate faster lithium ion diffusion, making LMFP an even more versatile option for next-generation battery technologies.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

185.0 °F

flash_point_c

85 °C

法规信息

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