94624
S-(1-氧代-2-吡啶基)-N,N,N′,N′-四甲基硫脲六氟磷酸盐
≥95.0% (NMR)
别名:
N,N,N′,N′-四甲基-S-(1-氧代-2-吡啶基)硫脲六氟磷酸盐, S-(2-吡啶基)-N,N,N′,N′-四甲基硫脲 N-氧化物六氟磷酸盐
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选择尺寸
关于此项目
经验公式（希尔记法）:
C10H16F6N3OPS
化学文摘社编号:
分子量:
371.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
InChI
1S/C10H16N3OS.F6P/c1-11(2)10(12(3)4)15-9-7-5-6-8-13(9)14;1-7(2,3,4,5)6/h5-8H,1-4H3;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.CN(C)\C(=[S+]\c1cccc[n+]1[O-])N(C)C
InChI key
UCOGEMMJHLHOAW-UHFFFAOYSA-N
assay
≥95.0% (NMR)
form
crystals
reaction suitability
reaction type: Coupling Reactions
mp
120-125 °C
application(s)
peptide synthesis
functional group
amine, thiourea
storage temp.
−20°C
Application
Reagent for:
Synthesis of inhibitors for PAD1, 3, and 4
Synthesis of enantiomerically pure vinylcyclopropylboronic esters
Synthesis of enantiomerically pure cyclopropane building blocks
Camphor-derived chiral auxiliary for hydroxyalkyl radicals
Solution and solid-phase coupling
Conversion of carboxylic acids to Weinreb amides and N-methoxy or N-benzoxy amides
Synthesis of inhibitors for PAD1, 3, and 4
Synthesis of enantiomerically pure vinylcyclopropylboronic esters
Synthesis of enantiomerically pure cyclopropane building blocks
Camphor-derived chiral auxiliary for hydroxyalkyl radicals
Solution and solid-phase coupling
Conversion of carboxylic acids to Weinreb amides and N-methoxy or N-benzoxy amides
Other Notes
非常活泼的肽偶联试剂
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
2-Mercaptopyridone 1-Oxide-Based Uronium Salts: New Peptide Coupling Reagents(1)(,)(2).
Miguel A. Bailén et al.
The Journal of organic chemistry, 64(24), 8936-8939 (2001-10-25)
F. Albericio et al.
Tetrahedron, 57, 9607-9607 (2001)
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