A24001
丙烯醛缩二乙醇
96%
别名:
3,3-二乙氧基丙烯
质量水平
方案
96%
表单
liquid
折射率
n20/D 1.398 (lit.)
沸点
125 °C (lit.)
密度
0.854 g/mL at 25 °C (lit.)
SMILES字符串
CCOC(OCC)C=C
InChI
1S/C7H14O2/c1-4-7(8-5-2)9-6-3/h4,7H,1,5-6H2,2-3H3
InChI key
MCIPQLOKVXSHTD-UHFFFAOYSA-N
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应用
丙烯醛二乙基缩醛广泛用于进行化学选择性 Heck 芳基化，合成 3-芳基丙酸酯或肉桂醛衍生物。
它也可用作合成天然产物如 (-)-(Z)-脱氧普卡灵、(-)-Laulimalide、botryodiplodin、neolaulimalide 和 isolaulimalide 的前体之一。
它也可用作合成天然产物如 (-)-(Z)-脱氧普卡灵、(-)-Laulimalide、botryodiplodin、neolaulimalide 和 isolaulimalide 的前体之一。
警示用语：
Danger
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
59.0 °F - closed cup
闪点(°C)
15 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Acrolein Diethyl Acetal: A Three?Carbon Homologating Reagent for the Synthesis of β?Arylpropanoates and Cinnamaldehydes by Heck Reaction Catalyzed by a Kaiser Oxime Resin Derived Palladacycle.
Alacid E and Najera C
The Journal of Organic Chemistry, 2008(18), 3102-3106 (2008)
Synthesis of (-)?(Z)?Deoxypukalide.
Donohoe TJ et al.
Angewandte Chemie (International Edition in English), 47(38), 7314-7316 (2008)
Stefano Parisotto et al.
Organic & biomolecular chemistry, 15(4), 884-893 (2017-01-04)
As part of our ongoing work on the synthesis of a new class of plant hormones named Strigolactones (SLs) and their analogues, we became interested in tracing bioactive molecules with red emitting BODIPY fluorophores in order to unravel signaling and
An efficient palladium-catalyzed synthesis of cinnamaldehydes from acrolein diethyl acetal and aryl iodides and bromides.
Battistuzzi G, et al.
Organic Letters, 5(5), 777-780 (2003)
Synthesis of (?)-and (−)-botryodiplodin using stereoselective radical cyclizations of acyclic esters and acetals.
Nouguier R et al.
Tetrahedron Asymmetry, 14(19), 3005-3018 (2003)
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