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A29585

烯丙基溴

Name: 烯丙基溴
Brand: ALDRICH

ReagentPlus^®, 99%, contains ≤1000 ppm propylene oxide as stabilizer

别名:

3-溴-1-丙烯

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关于此项目

线性分子式:

CH₂=CHCH₂Br

化学文摘社编号:

106-95-6

分子量:

120.98

UNSPSC Code:

12352101

NACRES:

NA.22

PubChem Substance ID:

24890713

EC Number:

203-446-6

Beilstein/REAXYS Number:

605308

MDL number:

MFCD00000244

Assay:

99%

Form:

liquid

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属性

vapor density

4.2 (vs air)

Quality Level

200

product line

ReagentPlus^®

assay

99%

form

liquid

autoignition temp.

554 °F

contains

≤1000 ppm propylene oxide as stabilizer

expl. lim.

7.3 %

refractive index

n20/D 1.469 (lit.)

bp

70-71 °C (lit.)

mp

−119 °C (lit.)

density

1.398 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

BrCC=C

InChI

1S/C3H5Br/c1-2-3-4/h2H,1,3H2

InChI key

BHELZAPQIKSEDF-UHFFFAOYSA-N

说明

Application

烯丙基溴可作为制备以下物质的反应剂：

在路易酸的作用下通过各种腈的 Barbier 型烯丙基化制备烯丙基酮。
使用锌粉作为催化剂，与醛类或酮类反应制备高烯丙醇。
通过氢化银团簇还原 C-C 键偶联制备 1,5-己二烯。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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pictograms

GHS02,GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H225,H301 + H331,H314,H340,H350,H400

pcodes

P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

30.2 °F - closed cup

flash_point_c

-1 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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分析证书(COA)

Lot/Batch Number

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Facile and efficient synthesis of homoallylic alcohols using allyl bromide and commercial zinc dust

Ranu BC, et al.

Tetrahedron Letters, 36(27), 4885-4888 (1995)

Gas-phase synthesis of [Ag4H]+ and its mediation of the C-C coupling of allyl bromide

Khairallah GN and O'Hair, Richard AJ

Angewandte Chemie (International Edition in English), 44(5), 728-731 (2005)

Synthesis of allyl ketone via Lewis acid promoted Barbier-type reaction

Lee Adam S-Y and Lin L-S

Tetrahedron Letters, 41(45), 8803-8806 (2000)

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全球贸易项目编号

货号	GTIN
A29585-1KG	04061833360095
A29585-5G	04061833360125
A29585-100G	04061833360088
A29585-3KG	04061833360101
A29585-500G	04061833360118