生物来源
synthetic
蒸汽密度
2.1 (vs air)
方案
≥95%
表单
liquid
自燃温度
842 °F
expl. lim.
23 %
折射率
n20/D 1.343 (lit.)
pH值（酸碱度）
4.0-5.0 (20 °C, 200 g/L)
沸点
32-34 °C (lit.)
mp
−100 °C (lit.)
密度
0.974 g/mL at 20 °C (lit.)
应用
flavors and fragrances
文件
see Safety & Documentation for available documents
食品过敏原
no known allergens
性状检查
fruity; plum
SMILES字符串
[H]C(=O)OC
InChI
1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI key
TZIHFWKZFHZASV-UHFFFAOYSA-N
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一般描述
Methyl formate finds application as a fumigant in raisins and dried currants.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-2.2 °F - closed cup
闪点(°C)
-19 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Winter R
A Consumer's Dictionary of Food Additives, 352-352 null
D Cain et al.
The Journal of organic chemistry, 66(18), 6092-6095 (2001-09-01)
Free-energy barriers of 9.85 and 11.91 +/- 0.15 kcal/mol at -70.8 degrees C were found by dynamic NMR spectroscopy for the E-to-Z and Z-to-E conversions, respectively, of methyl formate (1) enriched in 13C to 99% for the carbonyl carbon [methyl
T Sethre et al.
International archives of occupational and environmental health, 73(6), 401-409 (2000-09-28)
The aim of the study was to investigate the acute effects of experimental methylformate exposure on the nervous system. In an exposure chamber, 20 subjects were exposed to methylformate at 100 ppm [Swiss maximum allowable concentration (MAC)] for 8 h.
John F Marlier et al.
The Journal of organic chemistry, 70(5), 1737-1744 (2005-02-26)
Multiple isotope effects have been measured for the acid-catalyzed hydrolysis of methyl formate in 0.5 M HCl at 20 degrees C. The isotope effects in the present investigation include the carbonyl carbon (13k = 1.028 +/- 0.001), the carbonyl oxygen
Ivan Cornella et al.
The Journal of organic chemistry, 69(6), 2191-2193 (2004-04-03)
A total synthesis following the sequence in Scheme 1 confirms that porritoxin possesses revised structure 3, not the originally assigned 1. A key reaction was the use of iron pentacarbonyl to formylate an aryllithium when DMF and methyl formate proved
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