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Merck
CN

D90008

偶氮二甲酸二乙酯

别名:

DEAD

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线性分子式:
C2H5OCON=NCOOC2H5
化学文摘社编号:
分子量:
174.15
EC Number:
217-821-7
UNSPSC Code:
12352108
PubChem Substance ID:
Beilstein/REAXYS Number:
908662
MDL number:
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InChI key

FAMRKDQNMBBFBR-BQYQJAHWSA-N

InChI

1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

SMILES string

CCOC(=O)\N=N\C(=O)OCC

form

liquid

impurities

<3% dichloromethane

refractive index

n20/D 1.43 (lit.)

bp

106 °C/13 mmHg (lit.)

density

1.106 g/mL at 25 °C (lit.)

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Application

用于Mitsunobu 和Diels-Alder 反应,以及烯烃的烯丙基胺化的试剂

存储类别

1 - Explosive hazardous materials

pictograms

Exploding BombExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Expl. 1.1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Journal of Organic Chemistry, 58, 4979-4979 (1993)
F K Brown et al.
Journal of medicinal chemistry, 37(5), 674-688 (1994-03-04)
Systematic modification of the presumed P1 side chain in a series of (carboxyalkyl)amino-based inhibitors of matrix metalloproteinases enabled identification of the 2-(1,3-dihydro-1,3-dioxo-2H-benz[f]isoindol-2-yl)ethyl group as a preferred substituent imparting potent inhibition of the enzymes collagenase and gelatinase. It was subsequently found
The Journal of Organic Chemistry, 58, 5261-5261 (1993)
Gregory S Watson et al.
Acta biomaterialia, 21, 109-122 (2015-03-17)
Geckos, and specifically their feet, have attracted significant attention in recent times with the focus centred around their remarkable adhesional properties. Little attention however has been dedicated to the other remaining regions of the lizard body. In this paper we
Basile Siewe et al.
PloS one, 9(4), e92934-e92934 (2014-04-18)
During HIV infection, IL-10/IL-10 receptor and programmed death-1 (PD-1)/programmed death-1-ligand (PD-L1) interactions have been implicated in the impairment of cytotoxic T lymphocyte (CTL) activity. Despite antiretroviral therapy (ART), attenuated anti-HIV CTL functions present a major hurdle towards curative measures requiring

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