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Merck
CN

D90008

偶氮二甲酸二乙酯

别名:

DEAD

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线性分子式:
C2H5OCON=NCOOC2H5
化学文摘社编号:
分子量:
174.15
EC Number:
217-821-7
UNSPSC Code:
12352108
PubChem Substance ID:
Beilstein/REAXYS Number:
908662
MDL number:
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form

liquid

impurities

<3% dichloromethane

refractive index

n20/D 1.43 (lit.)

bp

106 °C/13 mmHg (lit.)

density

1.106 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)\N=N\C(=O)OCC

InChI

1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

InChI key

FAMRKDQNMBBFBR-BQYQJAHWSA-N

Application

用于Mitsunobu 和Diels-Alder 反应,以及烯烃的烯丙基胺化的试剂


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存储类别

1 - Explosive hazardous materials

pictograms

Exploding BombExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Expl. 1.1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Journal of Organic Chemistry, 58, 5261-5261 (1993)
The Journal of Organic Chemistry, 58, 4979-4979 (1993)
F K Brown et al.
Journal of medicinal chemistry, 37(5), 674-688 (1994-03-04)
Systematic modification of the presumed P1 side chain in a series of (carboxyalkyl)amino-based inhibitors of matrix metalloproteinases enabled identification of the 2-(1,3-dihydro-1,3-dioxo-2H-benz[f]isoindol-2-yl)ethyl group as a preferred substituent imparting potent inhibition of the enzymes collagenase and gelatinase. It was subsequently found