E22201
重氮乙酸乙酯
contains ≥13 wt. % dichloromethane
别名:
DAAE
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关于此项目
线性分子式:
N=N=CHCOOC2H5
化学文摘社编号:
分子量:
114.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
107654
Form:
liquid
form
liquid
Quality Level
contains
≥13 wt. % dichloromethane
refractive index
n20/D 1.46 (lit.)
bp
140-141 °C/720 mmHg (lit.)
mp
−22 °C (lit.)
solubility
water: slightly soluble
density
1.085 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CCOC(=O)C=[N+]=[N-]
InChI
1S/C4H6N2O2/c1-2-8-4(7)3-6-5/h3H,2H2,1H3
InChI key
YVPJCJLMRRTDMQ-UHFFFAOYSA-N
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Self-react. E - Skin Irrit. 2
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
116.6 °F - closed cup
flash_point_c
47 °C - closed cup
法规信息
危险化学品
此项目有
Ying Chen et al.
The Journal of organic chemistry, 69(7), 2431-2435 (2004-03-31)
Vitamin B(12) derivatives were found for the first time to be general and efficient catalysts for asymmetric cyclopropanation of alkenes with ethyl diazoacetate (EDA). Among several common derivatives, aquocobalamin (B(12a)) was shown to be the most effective catalyst for a
Barry M Trost et al.
Journal of the American Chemical Society, 131(5), 1674-1675 (2009-02-05)
Magnesium-catalyzed enantioselective aldol between ethyl diazoacetate and aromatic, aliphatic, and alpha,beta-unsaturated aldehydes affords alpha-diazo-beta-hydroxy-esters in high enantioselectivities. Aldol adducts resulting from this asymmetric transformation are versatile intermediates toward the synthesis of several ester containing chiral building blocks.
Lian-Biao Zhao et al.
The Journal of organic chemistry, 72(26), 10276-10278 (2007-11-29)
Copper-catalyzed [4 + 1] cycloaddition reaction of alpha,beta-acetylenic ketones with alpha-diazo esters offers an efficient, direct route to highly substituted furans. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.
Marianne Lenes Rosenberg et al.
The Journal of organic chemistry, 76(8), 2465-2470 (2011-03-19)
The performance of recently reported highly cis-diastereoselective Rh(I) cyclopropanation catalysts has been significantly improved by a systematic study of different reaction parameters (catalyst activation, solvent, temperature, stoichiometry). The catalyst efficiency and diastereoselectivity were enhanced by changing the activating agent from
Eva M Reingruber et al.
Journal of chromatography. A, 1255, 259-266 (2012-03-31)
Polymers, especially copolymers, are highly complex samples and, therefore, require various setups for their thorough characterization. In this work, one- and two-dimensional chromatographic approaches were applied to characterize two homopolymers and two dissimilar copolymers prepared by rhodium-mediated carbene polymerization using
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| E22201-5G | 04061833602522 |
| E22201-20G | 04061833602515 |
| E22201-1KG | 04061822415317 |
| E22201-100G | 04061833602508 |
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