M50001
甲基肼
98%
别名:
MMH
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关于此项目
线性分子式:
CH3NHNH2
化学文摘社编号:
分子量:
46.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-471-4
Beilstein/REAXYS Number:
635645
MDL number:
Assay:
98%
InChI key
HDZGCSFEDULWCS-UHFFFAOYSA-N
InChI
1S/CH6N2/c1-3-2/h3H,2H2,1H3
SMILES string
CNN
vapor density
1.6 (vs air)
vapor pressure
37.5 mmHg ( 20 °C)
assay
98%
autoignition temp.
385 °F
expl. lim.
97 %
refractive index
n20/D 1.4325 (lit.)
bp
88-90 °C (lit.)
density
0.875 g/mL at 20 °C (lit.)
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Application
甲基肼可用于诱导 β-三氟甲基-β,β-二取代烯酮的不对称需氧环氧化，合成对映选择性三氟甲基-取代的环氧化物。 也可用于合成1-甲基-3,5-二硝基-1H-1,2,4-三唑（DNMT），这是 TNT 炸药的替代物。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
flash_point_f
17.6 °F - closed cup
flash_point_c
-8 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
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Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β, β-Disubstituted Enones.
Kawai H, et al.
Angewandte Chemie (International ed. in English), 125(8), 2277-2281 (2013)
J M Pujolar et al.
BMC genomics, 16, 600-600 (2015-08-14)
Species showing complex life cycles provide excellent opportunities to study the genetic associations between life cycle stages, as selective pressures may differ before and after metamorphosis. The European eel presents a complex life cycle with two metamorphoses, a first metamorphosis
Y I Kim et al.
The American journal of pathology, 149(4), 1129-1137 (1996-10-01)
Folate deficiency enhances colorectal carcinogenesis in dimethylhydrazine-treated rats. Folate is an important mediator of DNA methylation, an epigenetic modification of DNA that is known to be dysregulated in the early stages of colorectal cancer. This study investigated the effect of
M Runge-Morris et al.
Toxicology and applied pharmacology, 125(1), 123-132 (1994-03-01)
The hydrazines represent an important class of xenobiotic agents encountered in the environment, in industrial settings, and in medical therapeutics. Agents with a hydrazine functionality are metabolized to toxic intermediates capable of damaging cellular macromolecules and stimulating proteolysis. Phenylhydrazine (PH)
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