M50001
甲基肼
98%
别名:
MMH
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关于此项目
线性分子式:
CH3NHNH2
化学文摘社编号:
分子量:
46.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-471-4
Beilstein/REAXYS Number:
635645
MDL number:
Assay:
98%
InChI key
HDZGCSFEDULWCS-UHFFFAOYSA-N
InChI
1S/CH6N2/c1-3-2/h3H,2H2,1H3
SMILES string
CNN
vapor density
1.6 (vs air)
vapor pressure
37.5 mmHg ( 20 °C)
assay
98%
autoignition temp.
385 °F
expl. lim.
97 %
refractive index
n20/D 1.4325 (lit.)
bp
88-90 °C (lit.)
density
0.875 g/mL at 20 °C (lit.)
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Application
甲基肼可用于诱导 β-三氟甲基-β,β-二取代烯酮的不对称需氧环氧化，合成对映选择性三氟甲基-取代的环氧化物。 也可用于合成1-甲基-3,5-二硝基-1H-1,2,4-三唑（DNMT），这是 TNT 炸药的替代物。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
flash_point_f
17.6 °F - closed cup
flash_point_c
-8 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β, β-Disubstituted Enones.
Kawai H, et al.
Angewandte Chemie (International ed. in English), 125(8), 2277-2281 (2013)
A safe and scalable process for the synthesis of melt-cast explosive 1-methyl-3, 5-dinitro-1H-1, 2, 4-triazole.
Luo J, et al.
Chemistry of Heterocyclic Compounds, 53(6-7), 714-718 (2017)
J M Pujolar et al.
BMC genomics, 16, 600-600 (2015-08-14)
Species showing complex life cycles provide excellent opportunities to study the genetic associations between life cycle stages, as selective pressures may differ before and after metamorphosis. The European eel presents a complex life cycle with two metamorphoses, a first metamorphosis
E S Lightcap et al.
Journal of medicinal chemistry, 39(3), 686-694 (1996-02-02)
(3-Hydroxybenzyl)hydrazine and methylhydrazine have been found to be potent slow-binding inhibitors of the pyridoxal 5-phosphate (PLP)-dependent enzyme gamma-aminobutyric acid aminotransferase (GABA-AT). Both compounds follow mechanism A (Morrison, J.F.; Walsh, C. T. Adv. Enzymol. 1988, 61, 201-301) which does not involve
M Runge-Morris et al.
Toxicology and applied pharmacology, 125(1), 123-132 (1994-03-01)
The hydrazines represent an important class of xenobiotic agents encountered in the environment, in industrial settings, and in medical therapeutics. Agents with a hydrazine functionality are metabolized to toxic intermediates capable of damaging cellular macromolecules and stimulating proteolysis. Phenylhydrazine (PH)
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