O4806
1-辛烯
98%
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关于此项目
线性分子式:
CH3(CH2)5CH=CH2
化学文摘社编号:
分子量:
112.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-893-7
Beilstein/REAXYS Number:
1734497
MDL number:
Assay:
98%
Form:
liquid
InChI key
KWKAKUADMBZCLK-UHFFFAOYSA-N
InChI
1S/C8H16/c1-3-5-7-8-6-4-2/h3H,1,4-8H2,2H3
SMILES string
CCCCCCC=C
vapor density
3.9 (vs air)
vapor pressure
36 mmHg ( 38 °C)
assay
98%
form
liquid
autoignition temp.
446 °F
expl. lim.
3.9 %
Quality Level
bp
122-123 °C (lit.)
mp
−101 °C (lit.)
density
0.715 g/mL at 25 °C (lit.)
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Application
1-辛烯为线性 α-烯烃主要用作共聚单体合成线性低密度聚乙烯 (LLDPE)。对 1-辛烯在不同催化剂上的氢甲酰化反应进行了广泛的研究。它也是通过环氧化反应合成重要的石油化工原料的重要来源。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
50.0 °F - closed cup
flash_point_c
10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Gas-liquid-liquid reaction engineering: hydroformylation of 1-octene using a water soluble rhodium complex catalyst
Purwanto, P and Delmas, H
Catalysis Today, 24(1-2), 135-140 (1995)
Catalytic epoxidation of 1-octene with diluted hydrogen peroxide. On the basic role of hydroxo complexes of platinum (II) and related species
Strukul, Giorgio and Michelin, Rino A
Journal of the American Chemical Society, 107(25), 7563-7569 (1985)
Hydroperoxide oxidations catalyzed by metals. IV. Molybdenum hexacarbonyl catalyzed epoxidation of 1-octene
Baker III, TN and Mains, GJ and Sheng, MN and Zajacek, JG
The Journal of Organic Chemistry, 38(6), 1145-1148 (1973)
Ionic phosphine ligands with cobaltocenium backbone: novel ligands for the highly selective, biphasic, rhodium-catalyzed hydroformylation of 1-octene in ionic liquids
Brasse CC, et al.
Organometallics, 19(19), 3818-3823 (2000)
Immobilization of a rhodium carbene complex to an amphiphilic block copolymer for hydroformylation of 1-octene under aqueous two-phase conditions
Zarka, M Tobias and Bortenschlager, Martin and Wurst, Klaus and Nuyken, Oskar and Weberskirch, Ralf
Organometallics, 23(21), 4817-4820 (2004)
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