方案
98%
沸点
285-290 °C (lit.)
mp
123-125 °C (lit.)
SMILES字符串
O=C1CCC(=O)N1
InChI
1S/C4H5NO2/c6-3-1-2-4(7)5-3/h1-2H2,(H,5,6,7)
InChI key
KZNICNPSHKQLFF-UHFFFAOYSA-N
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储存分类代码
11 - Combustible Solids
WGK
WGK 1
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Yutaka Sadakane et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 879(29), 3240-3246 (2011-04-08)
The major soluble eye lens protein, αA-crystallin, has a very long half-life. Thus, many post-translational modifications, including stereoinversion, have been found in its constituent amino acids. We determine the rates of β-linkage isomerization, which is the main reaction through the
Srinivasa Reddy Mothe et al.
The Journal of organic chemistry, 76(8), 2521-2531 (2011-03-15)
A one-pot, two-step method to prepare 3-halohydrofurans efficiently by TfOH-catalyzed hydroxylation/halocyclization of cyclopropyl methanols with H(2)O and N-halosuccinimide (NXS, X=1, Br, Cl) or Selectfluor is described. The reactions proceed rapidly under mild and operationally straightforward conditions with a catalyst loading
Ohgi Takahashi et al.
Chemistry & biodiversity, 7(6), 1630-1633 (2010-06-22)
The rapid racemization of aspartic acid (Asp) residues in peptides and proteins is due mainly to the succinimide intermediate. However, there should be another mechanism for Asp racemization without intermediacy of the succinimide. The direct H-atom abstraction from the C(alpha)-atom
Jennifer Zhang et al.
Analytical biochemistry, 410(2), 234-243 (2010-12-07)
A thermally stressed Fab molecule showed a significant increase of basic variants in imaged capillary isoelectric focusing (iCIEF) analysis. Mass analyses of the reduced protein found an increase in -18Da species from both light chain and heavy chain. A tryptic
Yann Desfougères et al.
Biomacromolecules, 12(1), 156-166 (2010-12-21)
Protein chemical degradations occur naturally into living cells as soon as proteins have been synthesized. Among these modifications, deamidation of asparagine or glutamine residues has been extensively studied, whereas the intermediate state, a succinimide derivative, was poorly investigated because of
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