InChI
1S/CN4O8/c6-2(7)1(3(8)9,4(10)11)5(12)13
InChI key
NYTOUQBROMCLBJ-UHFFFAOYSA-N
SMILES string
[O-][N+](=O)C([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O
vapor pressure
8.4 mmHg ( 20 °C)
refractive index
n20/D 1.438 (lit.)
bp
126 °C (lit.)
mp
13-14 °C (lit.)
density
1.637 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Application
烯醇硅醚和芳香族化合物的硝化试剂。用于硫化物到亚砜的光氧化反应。
Reactant involved in:
- Nitration of electrophilic alkenes
- Reactions with B-alkylcatecholboranes forming oxime ethers
- Heterocyclization of electrophilic alkenes
- Ring opening of aziridines
- Acts as an electron acceptor in the mechanism of aerobic visible light formic acid oxidation
- Reactions with vinyl ketones
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Irrit. 2 - Ox. Liq. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Synthesis, 1057-1057 (1993)
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Tetrahedron Letters, 34, 1859-1859 (1993)
J. Chem. Soc. Perkin Trans. II, 1719-1719 (1994)
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