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Merck
CN

T25003

Sigma-Aldrich

四硝基甲烷

别名:

TNM

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线性分子式:
C(NO2)4
化学文摘社编号:
分子量:
196.03
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽压

8.4 mmHg ( 20 °C)

折射率

n20/D 1.438 (lit.)

沸点

126 °C (lit.)

mp

13-14 °C (lit.)

密度

1.637 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

[O-][N+](=O)C([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O

InChI

1S/CN4O8/c6-2(7)1(3(8)9,4(10)11)5(12)13

InChI key

NYTOUQBROMCLBJ-UHFFFAOYSA-N

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应用

烯醇硅醚和芳香族化合物的硝化试剂。用于硫化物到亚砜的光氧化反应。
Reactant involved in:
  • Nitration of electrophilic alkenes
  • Reactions with B-alkylcatecholboranes forming oxime ethers
  • Heterocyclization of electrophilic alkenes
  • Ring opening of aziridines
  • Acts as an electron acceptor in the mechanism of aerobic visible light formic acid oxidation
  • Reactions with vinyl ketones

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Irrit. 2 - Ox. Liq. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Anthony Bayega et al.
BMC genomics, 21(1), 259-259 (2020-04-02)
The olive fruit fly, Bactrocera oleae, is the most important pest in the olive fruit agribusiness industry. This is because female flies lay their eggs in the unripe fruits and upon hatching the larvae feed on the fruits thus destroying
Valerie W Rusch et al.
Journal of thoracic oncology : official publication of the International Association for the Study of Lung Cancer, 11(12), 2112-2119 (2016-10-01)
The M component and TNM stage groupings for malignant pleural mesothelioma (MPM) have been empirical. The International Association for the Study of Lung Cancer developed a multinational database to propose evidence-based revisions for the eighth edition of the TNM classification
Vaibhav Gupta et al.
The Journal of thoracic and cardiovascular surgery, 156(2), 847-856 (2018-07-18)
Clinical, pathological, and molecular information combined with cancer stage in prognostication algorithms can offer more personalized estimates of survival, which might guide treatment choices. Our aim was to evaluate the quality of prognostication tools in esophageal cancer. We systematically searched
Synthesis, 1057-1057 (1993)
Tetrahedron Letters, 34, 1859-1859 (1993)

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