所有图片(2)

文件

T82805

三苯乙烯

Name: 三苯乙烯
Brand: ALDRICH

99%

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别名:

1,1,2-Triphenylethene, 1,1,2-Triphenylethylene, 1,1′,1′′-(1-Ethenyl-2-ylidene)tris[benzene], 1,2-Diphenylethenylbenzene, Benzilidenediphenylmethane, Ethene-1,1,2-triyltribenzene

线性分子式:

C₆H₅CH=C(C₆H₅)₂

CAS号:

58-72-0

分子量:

256.34

Beilstein:

1867462

EC 号:

200-395-1

MDL编号:

MFCD00004765

PubChem化学物质编号:

24900519

检测方案

99%

mp

69-71 °C (lit.)

SMILES string

c1ccc(cc1)\C=C(/c2ccccc2)c3ccccc3

InChI

1S/C20H16/c1-4-10-17(11-5-1)16-20(18-12-6-2-7-13-18)19-14-8-3-9-15-19/h1-16H

InChI key

MKYQPGPNVYRMHI-UHFFFAOYSA-N

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应用

三苯乙烯是一种芳香烃，可作为起始材料，通过以氟手性锰络合物为催化剂的不对称环氧化反应制备2,2,3-三苯基环氧乙烷。也可在MnO₂和NaOAc存在下，与乙酸酐反应制备二氢-4,5,5-三苯基-2(3H)-呋喃酮。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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T1503

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Speculation on the mechanism of action of triphenylethylene antioestrogens.

C D van den Koedijk et al.

Biochemical pharmacology, 47(11), 1927-1937 (1994-06-01)

Tamoxifen stimulates calcium entry into human platelets.

Yuliya Dobrydneva et al.

Journal of cardiovascular pharmacology, 50(4), 380-390 (2007-12-01)

The anti-estrogenic drug tamoxifen, which is used therapeutically for treatment and prevention of breast cancer, can lead to the development of thrombosis. We found that tamoxifen rapidly increased intracellular free calcium [Ca2+]i in human platelets from both male and female

The antioxidant action of ketoconazole and related azoles: comparison with tamoxifen and cholesterol.

H Wiseman et al.

Chemico-biological interactions, 79(2), 229-243 (1991-01-01)

The azole antifungal drug ketoconazole was found to inhibit Fe(III)-ascorbate dependent lipid peroxidation using either rat liver microsomes or ox-brain phospholipid liposomes as the substrate. It also inhibited microsomal peroxidation induced by the Fe(III)-ADP/NADPH system. The related azoles, miconazole and

Multiple mechanisms of protein kinase C inhibition by triphenylacrylonitrile antiestrogens.

E Bignon et al.

FEBS letters, 271(1-2), 54-58 (1990-10-01)

The activation of type I (gamma), II (beta) and III (alpha) protein kinase C (PKC) subspecies by phosphatidylserine (PS) and diacylglycerol (DAG) is inhibited by micromolar concentrations of triphenylacrylonitrile (TPE) antiestrogens. TPE A (with p-hydroxy and p-diethylaminoethoxy groups on the

Synthesis, purification and stability of no carrier added radioiodinated 1,1-bis(4-hydroxyphenyl)-2-iodo-2-phenylethylene (IBHPE), a prototype triphenylethylene estrogen-receptor binding radiopharmaceutical.

S J Gatley et al.

International journal of radiation applications and instrumentation. Part B, Nuclear medicine and biology, 18(7), 769-775 (1991-01-01)

A triphenylethylene compound [1,1-bis(4-hydroxyphenyl)-2-iodo-2-phenylethylene; IBHPE] has been labeled by halodestannylation with 123I at a specific radioactivity of 13,200 Ci/mmol (by in vitro receptor assay) after HPLC purification. The corresponding 80mBr-labeled compound (BrBHPE), which has a 3-fold higher affinity for the

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