CN
生物来源
synthetic
检测方案
98%
bp
290 °C (lit.)
mp
71-74 °C (lit.)
application(s)
flavors and fragrances
性状检查
coconut
SMILES string
O=C1OCc2ccccc12
InChI
1S/C8H6O2/c9-8-7-4-2-1-3-6(7)5-10-8/h1-4H,5H2
InChI key
WNZQDUSMALZDQF-UHFFFAOYSA-N
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示例
T1503
货号
-
25G
包装规格/数量
其它示例：
705578-5MG-PW
PL860-CGA/SHF-1EA
MMYOMAG-74K-13
1000309185
输入内容 1.000309185)
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Tsz-Ying Yuen et al.
Organic letters, 14(19), 5154-5157 (2012-09-29)
A highly convergent total synthesis of 7',8'-dihydroaigialospirol is described. Key steps of the synthesis include a Nozaki-Hiyama-Kishi (NHK) coupling of an iodoalkyne with an advanced phthalide-aldehyde and a remarkable one-pot acid-mediated global deprotection/spiroacetalization.
Juan Mangas-Sánchez et al.
Organic letters, 14(6), 1444-1447 (2012-03-08)
A straightforward synthesis of (S)-3-methylphthalides has been developed, with the key asymmetric step being the bioreduction of 2-acetylbenzonitriles. Enzymatic processes have been found to be highly dependent on the pH value, with acidic conditions being required to avoid undesired side
Zhishi Ye et al.
The Journal of organic chemistry, 75(17), 6043-6045 (2010-08-28)
A palladium-catalyzed addition of arylboronic acids to phthalaldehyde, followed by an intramolecular lactonization to access 3-substituted phthalides, is described. The procedure tolerates a series of functional groups, such as methoxyl, fluoro, chloro, and trifluoromethyl groups. It represents a procedure for
Jaganathan Karthikeyan et al.
Chemical communications (Cambridge, England), 47(37), 10461-10463 (2011-08-19)
A cobalt-catalyzed addition of aryl- and alkenylboronic acids to aldehydes and phthalaldehyde to give the corresponding biarylketones and 3-aryl phthalides in good to excellent yields in one pot is described.
Vatcharin Rukachaisirikul et al.
Journal of natural products, 75(5), 853-858 (2012-04-25)
Nine new fungal metabolites, one phthalide derivative, acremonide (1), and eight isocoumarin derivatives, acremonones A-H (2-9), were isolated from the mangrove-derived fungus Acremonium sp. PSU-MA70 together with 10 known compounds. Their structures were determined by NMR analysis. The known 8-deoxytrichothecin
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