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Merck
CN

8.00609

甲基丙烯酸缩水甘油酯

Technipur®

别名:

甲基丙烯酸环氧丙酯, 甲基丙烯酸甲酯缩水甘油

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经验公式(希尔记法):
C7H10O3
化学文摘社编号:
分子量:
142.15
NACRES:
NA.21
UNSPSC Code:
12162002
Beilstein/REAXYS Number:
2506
MDL number:
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产品名称

甲基丙烯酸缩水甘油酯, Technipur®

SMILES string

CC(=C)C(=O)OCC1CO1

InChI

1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3

InChI key

VOZRXNHHFUQHIL-UHFFFAOYSA-N

grade

synthesis grade

vapor pressure

4.2 hPa ( 25 °C)

refractive index

n20/D 1.449 (lit.)

bp

189 °C (lit.)

mp

<-60 °C

density

1.042 g/mL at 25 °C (lit.)
1.07 g/cm3 at 25 °C

Quality Level

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Application

2,3-Epoxypropyl methacrylate can be used as a monomer unit in polymer industries to produce poly (glycidyl methacrylate)(PGMA) for various uses in electronic and biomedical applications. The presence of epoxide group in PGMA allows it to be modified by a variety of functionalities such as amine-epoxy, thiol-epoxy, azide-epoxy, and acid-epoxy via nucleophilic ring-opening reactions. This overall flexibility in the functionalization of PGMA is because of the controlled polymerization of 2,3-epoxypropyl methacrylate monomer via free radical polymerization. Thus, PGMA is one of the most adaptable reactive scaffolds in polymer chemistry due to the long shelf life of the resulting polymers.

It is also used to prepare poly(n-butyl methacrylate-co-glycidyl methacrylate) copolymers, which find applications in adhesives, surface coatings, and electrical devices in various polymeric industries. The presence of epoxy groups and flexible butyl groups in epoxy resin-modified copolymers increases its mechanical properties, impact strength, and fracture elongation.

General description

2,3-Epoxypropyl methacrylate is a methacrylic acid/glycidol ester. It is used as a monomer to produce polymers based on glycidyl methacrylate (GMA). It is also a dual functionality (epoxy and methacrylate) monomer, thus offering the opportunity for chemical modification of the parent polymer for various applications.

Legal Information

Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1C - Skin Sens. 1 - STOT RE 1 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

法规信息

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Epoxy-functional thermoplastic copolymers and their incorporation into a thermosetting resin
Sweet KR, et al.
Journal of Applied Polymer Science, 138(26), 50608-50608 (2021)
Shi G, et al.
Polymer-Plastics Technology and Engineering, 54(9), 881-888 (2015)
Post-polymerization modification reactions of poly(glycidyl methacrylate)s
Muzammil EM, et al.
Royal Society of Chemistry Advances, 7, 55874-55884 (2017)
Diblock copolymers, triblock copolymers andmodel networks synthesized by sequential anionic polymerization of styrene and 2,3-epoxypropyl methacrylate
Hild G and Lamps J-P
Polymer, 39(12), 2637-2649 (1998)
Self-assembly and applications of poly(glycidyl methacrylate)s and their derivatives
Li Q-L, et al.
Chemical Communications (Cambridge, England), 87 (2014)

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