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8.06722

Nickel(II) chloride

Name: Nickel(II) chloride
Brand: MM

anhydrous for synthesis

别名:

Nickel(II) chloride, Nickel dichloride

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About This Item

经验公式（希尔记法）:

Cl₂Ni

CAS Number:

7718-54-9

分子量:

129.60

MDL编号:

MFCD18909718

UNSPSC代码:

12352302

EC索引号:

231-743-0

NACRES:

NA.22

等级

synthesis grade

质量水平

200

蒸汽压

1.33 hPa ( 671 °C)

表单

powder

效能

105 mg/kg LD₅₀, oral (Rat)

pH值（酸碱度）

4 (20 °C, 500 g/L in H₂O)

mp

1009 °C

密度

3.55 g/cm³

储存温度

2-30°C

SMILES字符串

[Ni+2].[Cl-].[Cl-]

InChI

1S/2ClH.Ni/h2*1H;/q;;+2/p-2

InChI key

QMMRZOWCJAIUJA-UHFFFAOYSA-L

应用

Nickel(II) chloride can be used as a catalyst:

To synthesize acyclic and cyclic dithioacetals via thioacetalization of aldehydes.
To prepare α-aminonitrile derivatives via a one-pot, three-component coupling reaction of aldehydes, amines, and trimethylsilyl cyanide.
In the hydrodefluorination of fluoroarenes in the presence of lithium triethylborohydride.

分析说明

Assay (complexometric): 98.0 - 102.0 %
Loss on drying (150 °C; 3h): ≤ 1.0 %

象形图

GHS06,GHS08,GHS09

警示用语：

Danger

危险声明

H301 + H331 - H315 - H317 - H334 - H341 - H350i - H360D - H372 - H410

预防措施声明

P202 - P273 - P280 - P301 + P310 - P302 + P352 - P304 + P340 + P311

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

靶器官

Lungs

储存分类代码

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)