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Merck
CN

8.07027

1,2-Propylene oxide

for synthesis

别名:

1,2-Propylene oxide, 1,2-Epoxypropane, Methyloxirane

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关于此项目

经验公式(希尔记法):
C3H6O
化学文摘社编号:
分子量:
58.08
UNSPSC Code:
12352005
EC Index Number:
200-879-2
NACRES:
NA.22
MDL number:
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产品名称

1,2-Propylene oxide, for synthesis

SMILES string

O1C(C1)C

InChI

1S/C3H6O/c1-3-2-4-3/h3H,2H2,1H3

InChI key

GOOHAUXETOMSMM-UHFFFAOYSA-N

vapor pressure

585 hPa ( 20 °C)

assay

≥99.0% (GC)

form

liquid

autoignition temp.

430 °C

potency

380 mg/kg LD50, oral (Rat)
1245 mg/kg LD50, skin (Rabbit)

expl. lim.

1.9-36 % (v/v)

reaction suitability

reaction type: C-C Bond Formation

kinematic viscosity

0.37 cSt(20 °C)

mp

-112 °C

transition temp

flash point -38 °C

density

0.83 g/cm3 at 20 °C

Quality Level

Analysis Note

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.828 - 0.832
Identity (IR): passes test

Application


  • Enhanced poly(propylene carbonate) synthesis: Enhanced poly(propylene carbonate) materials were developed through a one-pot synthesis from carbon dioxide, propylene oxide, and a carboxylic dianhydride, showing significant improvements in yield strength when the feed molar ratio of dianhydride to propylene oxide was increased (X Chen et al., 2018).

  • Copolymerization with carbon dioxide: A study on the copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a cobalt salen complex demonstrated efficient synthesis without forming ether linkages (JY Jeon et al., 2014).

  • Polymer architectures: Innovative polymer architectures were explored in the synthesis of poly(ethylene oxide), propylene oxide, and other alkylene oxides, which include novel bioconjugation techniques (J Herzberger et al., 2016).

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 1 - Muta. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-36.4 °F - Equilibrium method

flash_point_c

-38 °C - Equilibrium method

法规信息

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