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Merck
CN

13-0730

六亚甲基二胺

SAJ first grade, ≥98.0%

别名:

1,6-二氨基己烷, 1,6-己二胺, HMDA

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线性分子式:
NH2(CH2)6NH2
化学文摘社编号:
分子量:
116.20
EC Number:
204-679-6
UNSPSC Code:
12352116
PubChem Substance ID:
Beilstein/REAXYS Number:
1098307
MDL number:
Assay:
≥98.0%
Grade:
SAJ first grade
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InChI

1S/C6H16N2/c7-5-3-1-2-4-6-8/h1-8H2

InChI key

NAQMVNRVTILPCV-UHFFFAOYSA-N

SMILES string

NCCCCCCN

grade

SAJ first grade

vapor density

4 (vs air)

assay

≥98.0%

form

solid

expl. lim.

6.3 %

availability

available only in Japan

dilution

(for analytical testing)

refractive index

n20/D 1.439 (lit.)

pH

12.4 (25 °C, 100 g/L)

mp

42-45 °C (lit.)

density

0.89 g/mL at 25 °C (lit.)

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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

176.0 °F - closed cup

flash_point_c

80 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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历史批次信息供参考:

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Lot/Batch Number

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Linda G T Gaines et al.
Journal of environmental monitoring : JEM, 13(1), 119-127 (2010-10-28)
Although urinary 1,6-hexamethylene diamine (HDA) is a useful biomarker of exposure to 1,6-hexamethylene diisocyanate (HDI), a large degree of unexplained intra- and inter-individual variability exists between estimated HDI exposure and urine HDA levels. We investigated the effect of individual and
Richard F G Fröhlich et al.
Carbohydrate research, 346(12), 1592-1598 (2011-06-08)
Two simple and reliably accessible intermediates, N-carboxypentyl- and N-aminohexyl-1-deoxy-D-galactonojirimycin were employed for the synthesis of a set of terminally N-dansyl substituted derivatives. Reaction of the terminal carboxylic acid of N-carboxypentyl-1-deoxy-D-galactonojirimycin with N-dansyl-1,6-diaminohexane provided the chain-extended fluorescent derivative. Employing bis(6-dansylaminohexyl)amine, the
Wei-Chiang Chen et al.
ACS applied materials & interfaces, 1(8), 1821-1826 (2010-04-02)
Solvent microenvironments are formed around individual single-walled carbon nanotubes (SWNTs) by mixing SWNT suspensions with water-immiscible organic solvents. These microenvironments are used to encapsulate the SWNTs with the monomer sebacoyl chloride. Hexamethylene diamine is then injected into the aqueous phase
Junseok Yeom et al.
Bioconjugate chemistry, 21(2), 240-247 (2010-01-19)
A novel, biocompatible, and nontoxic dermal filler using hyaluronic acid (HA) hydrogels was successfully developed for tissue augmentation applications. Instead of using highly reactive cross-linkers such as divinyl sulfone (DVS) for Hylaform, 1,4-butanediol diglycidyl ether (BDDE) for Restylane, and 1,2,7,8-diepoxyoctane
Linda G T Gaines et al.
The Annals of occupational hygiene, 54(6), 678-691 (2010-06-10)
Urinary 1,6-hexamethylene diamine (HDA) may serve as a biomarker for systemic exposure to 1,6-hexamethylene diisocyanate (HDI) in occupationally exposed populations. However, the quantitative relationships between dermal and inhalation exposure to HDI and urine HDA levels have not been established. We

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