24-2700
三氯氧磷(V)
SAJ special grade, 99.0-100.5%
别名:
三氯氧化磷(V), 磷酰三氯
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关于此项目
线性分子式:
POCl3
化学文摘社编号:
分子量:
153.33
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
233-046-7
MDL number:
Assay:
99.0-100.5%
Grade:
SAJ special grade
Bp:
105.8 °C (lit.)
Vapor pressure:
104 mmHg ( 50 °C), 28 mmHg ( 20 °C)
InChI key
XHXFXVLFKHQFAL-UHFFFAOYSA-N
InChI
1S/Cl3OP/c1-5(2,3)4
SMILES string
ClP(Cl)(Cl)=O
grade
SAJ special grade
vapor density
5.3 (vs air)
vapor pressure
104 mmHg ( 50 °C), 28 mmHg ( 20 °C)
assay
99.0-100.5%
form
liquid
availability
available only in Japan
dilution
(for analytical testing)
pH
1 (20 °C)
bp
105.8 °C (lit.)
mp
1.25 °C (lit.)
density
1.645 g/mL at 25 °C (lit.)
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation
target_organs
Respiratory Tract
supp_hazards
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Eric S Melby et al.
PloS one, 6(4), e18420-e18420 (2011-04-13)
Phosphorus (P) has only one stable isotope and therefore tracking P dynamics in ecosystems and inferring sources of P loading to water bodies have been difficult. Researchers have recently employed the natural abundance of the ratio of (18)O/(16)O of phosphate
Simple coupling reaction between amino acids and weakly nucleophilic heteroaromatic amines.
Gilles Quéléver et al.
Journal of combinatorial chemistry, 6(5), 695-698 (2004-09-14)
Changjiang Yu et al.
Angewandte Chemie (International ed. in English), 51(31), 7688-7691 (2012-06-26)
Three for one: Pyrrolyldipyrromethenes having different functional groups were efficiently synthesized from POCl(3)-promoted condensations between 5-chloro-2-formylpyrrole or isoindole derivatives and suitable pyrrole or indole fragments through a novel nucleophilic aromatic substitution of the initially formed protonated azafulvene rings.
D M Badgujar et al.
Journal of hazardous materials, 172(1), 276-279 (2009-08-12)
1,2-Bis(2,4,6-trinitrophenyl) hydrazine (3) is one of the precursors in the synthesis of an important energetic material viz., hexanitrazobenzene. The simple and convenient lab scale synthesis of title compound (3) was carried out by the condensation of picryl chloride (2) with
Bo Qin et al.
Chemistry, an Asian journal, 6(12), 3298-3305 (2011-07-23)
POCl(3)-mediated one-pot macrocyclization allows the highly selective formation of five-residue macrocycles that are rigidified by internally placed intramolecular hydrogen bonds. Mechanistic investigation by using tailored competition experiments and kinetic simulation provides a comprehensive model, supporting a chain-growth mechanism underlying the
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