24-2830
三氯化磷
CP
别名:
氯化磷(III)
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关于此项目
线性分子式:
PCl3
化学文摘社编号:
分子量:
137.33
EC Number:
231-749-3
UNSPSC Code:
12352300
PubChem Substance ID:
Beilstein/REAXYS Number:
969177
MDL number:
Grade:
CP
Bp:
74-78 °C (lit.)
Vapor pressure:
100 mmHg ( 20 °C), 125 mmHg ( 25 °C), 385 mmHg ( 55 °C)
InChI key
FAIAAWCVCHQXDN-UHFFFAOYSA-N
InChI
1S/Cl3P/c1-4(2)3
SMILES string
ClP(Cl)Cl
grade
CP
vapor density
4.75 (vs air)
vapor pressure
100 mmHg ( 20 °C), 125 mmHg ( 25 °C), 385 mmHg ( 55 °C)
form
liquid
availability
available only in Japan
dilution
(for analytical testing)
refractive index
n20/D 1.5148 (lit.)
bp
74-78 °C (lit.)
mp
−112 °C (lit.)
density
1.574 g/mL at 20 °C (lit.)
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation
target_organs
Respiratory Tract
supp_hazards
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
D Zicane et al.
International journal of peptide and protein research, 48(1), 56-58 (1996-07-01)
N-Formylpyroglutamic acid-7-amido-4-methylcoumarine and pyroglutamyl-pyroglutamic acid-7-amido-4-methylcoumarin are the major products in the synthesis of pyroglutamic acid-7-amido-4-methylcoumarin by phosphorus pentachloride in dimethylformamide and dicyclohexylcarbodiimide under pyridine activation.
Núria Mont et al.
Molecular diversity, 13(1), 39-45 (2008-11-28)
A protocol for the synthesis of N-substituted 2-hydro-4-amino-pyrido[2,3-d]pyrimidin-7(8H)-ones (11) is described. Thus, the formylation of a 2-aminopyridone 12 in 85% formic acid/Ac(2)O, proceeding via in situ cyclization to the intermediate formamide 13, affords the corresponding 2-hydro-4-oxo-pyridopyrimidine 14, which is converted
Action of phosphorus pentachloride on p-sulphonamido benzoic acid.
A D KEMP
Nature, 159(4041), 509-509 (1947-04-12)
Petri A Turhanen et al.
Organic & biomolecular chemistry, 1(18), 3223-3226 (2003-10-07)
Methods for the preparation of mixed tetra-amide esters 1 and 2, the partial amide ester 3, and tri- and P,P-diamides 4 and 5 from monophosphorus spieces 12, 8 and 9, respectively, were developed. Compounds 8 and 9 were obtained from
Phosphorus trichloride-mediated and microwave-assisted synthesis of a small collection of amides bearing strong electron-withdrawing group substituted anilines.
Matteo Colombo et al.
Journal of combinatorial chemistry, 11(3), 335-337 (2009-03-31)
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