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Merck
CN

24-2830

Sigma-Aldrich

三氯化磷

CP

别名:

氯化磷(III)

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线性分子式:
PCl3
化学文摘社编号:
分子量:
137.33
Beilstein:
969177
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
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等级

CP

蒸汽密度

4.75 (vs air)

蒸汽压

100 mmHg ( 20 °C)
125 mmHg ( 25 °C)
385 mmHg ( 55 °C)

表单

liquid

存货情况

available only in Japan

dilution

(for analytical testing)

折射率

n20/D 1.5148 (lit.)

沸点

74-78 °C (lit.)

mp

−112 °C (lit.)

密度

1.574 g/mL at 20 °C (lit.)

SMILES字符串

ClP(Cl)Cl

InChI

1S/Cl3P/c1-4(2)3

InChI key

FAIAAWCVCHQXDN-UHFFFAOYSA-N

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Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation

靶器官

Respiratory Tract

补充剂危害

储存分类代码

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Petri A Turhanen et al.
Organic & biomolecular chemistry, 1(18), 3223-3226 (2003-10-07)
Methods for the preparation of mixed tetra-amide esters 1 and 2, the partial amide ester 3, and tri- and P,P-diamides 4 and 5 from monophosphorus spieces 12, 8 and 9, respectively, were developed. Compounds 8 and 9 were obtained from
Phosphorus trichloride-mediated and microwave-assisted synthesis of a small collection of amides bearing strong electron-withdrawing group substituted anilines.
Matteo Colombo et al.
Journal of combinatorial chemistry, 11(3), 335-337 (2009-03-31)
L Yu et al.
Amino acids, 28(4), 369-372 (2005-05-13)
The reactions of phosphorus trichloride with various amino acids afford the pentacoordinated spirophosphoranes. The reaction procedures were traced by (31)P NMR spectra techniques. A new crystal structure of alanine derivative was characterized, which is a slightly distorted TBP structure. Besides
T Kapias et al.
Journal of hazardous materials, 81(3), 223-249 (2001-02-13)
Phosphorus trichloride and oxychloride are aggressive materials, widely used in the process industries. On escape to the atmosphere they create toxic clouds that may cause serious damage to people and to the environment. When spilled onto the ground they create
A Eldad et al.
Burns : journal of the International Society for Burn Injuries, 18(4), 340-341 (1992-08-01)
A 51-year-old chemical engineer sustained phosphorous pentachloride partial skin thickness burns over 20 per cent of his body surface area. Although macroscopically and microscopically the wound seemed to be superficial, the course of clinical healing of this injury was very

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