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01510

1-O-乙酰基-2,3,5-O-三苯甲酰基-β-D-呋喃核糖

Name: 1-O-乙酰基-2,3,5-O-三苯甲酰基-β-<SC>D</SC>-呋喃核糖
Brand: SIAL

purum, ≥97.0% (TLC)

别名:

1-乙酰基-2,3,5-三苯甲酰基-β-D-呋喃核糖

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关于此项目

经验公式（希尔记法）:

C₂₈H₂₄O₉

化学文摘社编号:

6974-32-9

分子量:

504.48

EC Number:

230-220-4

UNSPSC Code:

12352200

PubChem Substance ID:

24844890

Beilstein/REAXYS Number:

100243

MDL number:

MFCD00005357

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grade

purum

assay

≥97.0% (TLC)

optical activity

[α]20/D +44±1°, c = 0.5% in chloroform

mp

128-130 °C

SMILES string

CC(=O)O[C@@H]1O[C@H](COC(=O)c2ccccc2)[C@@H](OC(=O)c3ccccc3)[C@H]1OC(=O)c4ccccc4

InChI

1S/C28H24O9/c1-18(29)34-28-24(37-27(32)21-15-9-4-10-16-21)23(36-26(31)20-13-7-3-8-14-20)22(35-28)17-33-25(30)19-11-5-2-6-12-19/h2-16,22-24,28H,17H2,1H3/t22-,23-,24-,28-/m1/s1

InChI key

GCZABPLTDYVJMP-CBUXHAPBSA-N

Other Notes

核糖衍生物，用于核苷的合成；与 Me₃SiC 产生 1-氰化反应

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

涉药品监管产品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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M. Saneyoshi et al.

Chemical & Pharmaceutical Bulletin, 27, 2518-2518 (1979)

A. Matsuda et al.

Synthesis, 748-748 (1981)

K. Utimoto et al.

Tetrahedron Letters, 23, 237-237 (1982)

The use of iodotrimethylsilane in nucleosidation procedure.

Z Tocik et al.

Nucleic acids research, 8(20), 4755-4761 (1980-10-24)

1-O-Acetyl-2,3,5-tri-O-benzoyl-beta-D-ribofuranose (I) was reacted with iodotrimethylsilane (II) and the product, the glycosyl iodide, was coupled with silylated uracil to afford 1-(2,3,5-tri-O-benzoyl-beta-D-ribofuranosyl)uracil (III; 89%), with silyated cytosine to afford, on subsequent acetylation, 1-(2,3,5-tri-O-benzoyl-beta-0D-ribofuranosyl)-4-acetamido-2-(1H)-pyrimidinone (IVb; 81%), and with chloromercuri-N-benzoyl-adenine to afford Va

A general synthesis of N-glycosides. I. Synthesis of pyrimidine nucleosides.

U Niedballa et al.

The Journal of organic chemistry, 39(25), 3654-3660 (1974-12-13)

全球贸易项目编号

货号	GTIN
8416200250	04022536884653
C105805-25G	04061833460627
PHR2898-3X1.2ML	04065266458633
8416200050	04022536647005
1154605-2X1ML	04061837842696
C105805-100G	04061833460610
C105805-5G	04061833460634

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