04175
涕灭威-(N-甲基-13C,d3 氨甲酰-13C)亚砜
PESTANAL®, analytical standard
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关于此项目
经验公式（希尔记法）:
13C2C5D3H11N2O3S
化学文摘社编号:
分子量:
211.27
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
77101502
MDL number:
InChI key
BXPMAGSOWXBZHS-FONWFMSDSA-N
SMILES string
[2H][13C]([2H])([2H])N[13C](=O)O\N=C\C(C)(C)S(C)=O
InChI
1S/C7H14N2O3S/c1-7(2,13(4)11)5-9-12-6(10)8-3/h5H,1-4H3,(H,8,10)/b9-5+/i3+1D3,6+1
grade
analytical standard
isotopic purity
≥99.0 atom % 13C, ≥98.0 atom % D
product line
PESTANAL®
assay
≥98.5% (HPLC)
shelf life
limited shelf life, expiry date on the label
application(s)
agriculture
environmental
format
neat
mass shift
M+5
Quality Level
General description
Aldicarb-(N-methyl-13C,d3, carbamoyl-13C) sulfoxide is an isotope-labeled analog of the carbamate pesticide, aldicarb.
Application
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
Analysis Note
identification (LC-MS): identity conforms
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Oral - Aquatic Acute 1
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Aldicarb poisoning
Ragouc-Sengler C, et al.
Human & Experimental Toxicology, 19(12), 657-662 (2000)
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