04907
N,N-双-[(R)-1-苯基乙基]二苯并[d,f][1,3,2]二氧杂膦-6-胺
≥99.0%
别名:
(R,R)-N-(5,7-二氧杂-6-磷杂二苯并[a,c]环庚烯-6-基)双(1-苯乙基)胺, O,O′-(2,2′-联苯二基)N,N-双[(R)-1-苯基乙基]亚磷酰胺, BIPOL-A1(R)
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选择尺寸
关于此项目
经验公式（希尔记法）:
C28H26NO2P
化学文摘社编号:
分子量:
439.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3
SMILES string
C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5
InChI key
JISGHECLGYELKD-UHFFFAOYSA-N
assay
≥99.0%
optical purity
enantiomeric ratio: ≥97.0:3.0
reaction suitability
reaction type: click chemistry
mp
99-102 °C
functional group
amine, phenyl
Quality Level
Application
N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
- In the asymmetric hydrovinylation of 1,3-diene.
- In the 1,4-asymmetric conjugate addition of 3-substituted cyclohexenones catalyzed by copper.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Asymmetric Sequential Cu-Catalyzed 1, 6/1, 4-Conjugate Additions of Hard Nucleophiles to Cyclic Dienones: Determination of Absolute Configurations and Origins of Enantioselectivity
Blons C, et al.
Chemistry?A European Journal , 23(31), 7515-7525 (2017)
Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control
Tenneti S, et al.
Journal of the American Chemical Society, 140(31), 9868-9881 (2018)
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