05512
(S)-(-)-1-苯乙醇
≥98.5% (sum of enantiomers, GC)
别名:
(-)-甲基苯基甲醇, (S)-(− 秒 -苯乙醇, (S)-(-)-α-甲基苄醇
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关于此项目
经验公式（希尔记法）:
C8H10O
化学文摘社编号:
分子量:
122.16
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2039797
Assay:
≥98.5% (sum of enantiomers, GC)
Form:
liquid
Quality Segment
assay
≥98.5% (sum of enantiomers, GC)
form
liquid
optical activity
[α]/D −45±2°, c = 5% in methanol
optical purity
enantiomeric ratio: ≥97:3 (GC)
refractive index
n
bp
88-89 °C/10 mmHg (lit.)
mp
9-11 °C (lit.)
density
1.012 g/mL at 20 °C (lit.)
functional group
hydroxyl, phenyl
SMILES string
C[C@H](O)c1ccccc1
InChI
1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-/m0/s1
InChI key
WAPNOHKVXSQRPX-ZETCQYMHSA-N
General description
(S)-(-)-1-Phenylethanol can be prepared from acetophenone via enantioselective bioreduction in the presence of Rhizopus arrhizus as a biocatalyst.
Application
(S)-(-)-1-Phenylethanol can be used as:
- A starting material to prepare (1S,3R,4S)-1-methyl-3,4-diphenyl-3,4-dihydro-1H-isochromene-3,4-diol (a cyclic hemiacetal) by reacting with benzil via dilithiation reaction.
- A chiral solvent in the symmetric synthesis of substituted spiroundecenetriones via amino acid-catalyzed domino Knoevenagel/Diels-Alder reactions.
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Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
警示词
Warning
危险代码
怎么回事？
WGK 3
PPE（个人防护设备）
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter