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Merck
CN

05860

Sigma-Aldrich

烯丙基溴

puriss., ≥99.0% (GC)

别名:

3-溴-1-丙烯

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线性分子式:
CH2=CHCH2Br
化学文摘社编号:
分子量:
120.98
Beilstein:
605308
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
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蒸汽密度

4.2 (vs air)

等级

puriss.

方案

≥99.0% (GC)

自燃温度

554 °F

包含

silver wool as stabilizer

expl. lim.

7.3 %

折射率

n20/D 1.469 (lit.)
n20/D 1.469

沸点

70-71 °C (lit.)

mp

−119 °C (lit.)

密度

1.398 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

BrCC=C

InChI

1S/C3H5Br/c1-2-3-4/h2H,1,3H2

InChI key

BHELZAPQIKSEDF-UHFFFAOYSA-N

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警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

30.2 °F - closed cup

闪点(°C)

-1 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

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Kiew-Ching Lee et al.
Chemical communications (Cambridge, England), (40)(40), 4209-4211 (2006-10-13)
The total synthesis of natural (4R,5R)-antillatoxin and its analog (4S,5S)-antillatoxin has been achieved; the optically pure key intermediates were prepared from indium mediated allylation of either primary or secondary allylic bromide with aldehyde in aquoues media, followed by highly selective
Martín Fañanás-Mastral et al.
Chemical communications (Cambridge, England), 47(20), 5843-5845 (2011-04-20)
A stereoselective synthesis of 1,2-hydroxyalkyl moieties is described herein. These valuable building blocks are obtained with complete regiocontrol and excellent stereocontrol both for the syn or the anti products, by choosing the appropriate enantiomer of the ligand in a copper-catalyzed
M Durandetti et al.
Organic letters, 3(13), 2073-2076 (2001-06-22)
[reaction: see text] Electrochemical arylation of arenecarboxaldehydes using an iron sacrificial anode in the presence of chromium and nickel catalysts afforded the corresponding arylated secondary alcohols in moderate to good yields. The chromium and nickel salts as catalysts are obtained
Konrad Koszinowski
Journal of the American Chemical Society, 132(17), 6032-6040 (2010-04-10)
Solutions of allyl indium reagents formed in the reactions of indium with allyl bromide and allyl iodide, respectively, in N,N-dimethylformamide, tetrahydrofuran, and water were analyzed by a combination of electrospray-ionization mass spectrometry, temperature-dependent (1)H NMR spectroscopy, and electrical conductivity measurements.
E Eder et al.
Chemico-biological interactions, 61(2), 97-108 (1987-02-01)
The in vitro binding of three allyl compounds, allyl methanesulphonate, allyl bromide and allyl chloride to DNA from salmon sperm was investigated. Kinetic DNA-alkylation measurements revealed significant differences between the strongly alkylating allyl methanesulphonate and allyl bromide with half-life values

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