05860
烯丙基溴
puriss., ≥99.0% (GC)
别名:
3-溴-1-丙烯
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线性分子式:
CH2=CHCH2Br
化学文摘社编号:
分子量:
120.98
EC Number:
203-446-6
UNSPSC Code:
12352101
PubChem Substance ID:
Beilstein/REAXYS Number:
605308
MDL number:
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
SMILES string
BrCC=C
vapor density
4.2 (vs air)
grade
puriss.
assay
≥99.0% (GC)
autoignition temp.
554 °F
contains
silver wool as stabilizer
expl. lim.
7.3 %
bp
70-71 °C (lit.)
mp
−119 °C (lit.)
density
1.398 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
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Martín Fañanás-Mastral et al.
Chemical communications (Cambridge, England), 47(20), 5843-5845 (2011-04-20)
A stereoselective synthesis of 1,2-hydroxyalkyl moieties is described herein. These valuable building blocks are obtained with complete regiocontrol and excellent stereocontrol both for the syn or the anti products, by choosing the appropriate enantiomer of the ligand in a copper-catalyzed
Kiew-Ching Lee et al.
Chemical communications (Cambridge, England), (40)(40), 4209-4211 (2006-10-13)
The total synthesis of natural (4R,5R)-antillatoxin and its analog (4S,5S)-antillatoxin has been achieved; the optically pure key intermediates were prepared from indium mediated allylation of either primary or secondary allylic bromide with aldehyde in aquoues media, followed by highly selective
Konrad Koszinowski
Journal of the American Chemical Society, 132(17), 6032-6040 (2010-04-10)
Solutions of allyl indium reagents formed in the reactions of indium with allyl bromide and allyl iodide, respectively, in N,N-dimethylformamide, tetrahydrofuran, and water were analyzed by a combination of electrospray-ionization mass spectrometry, temperature-dependent (1)H NMR spectroscopy, and electrical conductivity measurements.
Marcel S F Lie Ken Jie et al.
Lipids, 38(12), 1293-1297 (2004-02-12)
A methylene-interrupted C18 keto-acetylenic fatty ester (methyl 12-oxo-9-octadecynoate) was obtained from methyl ricinoleate by bromination-dehydrobromination followed by oxidation. Reaction of methyl 12-oxo-9-octadecynoate with bis(benzonitrile) palladium(II) chloride, allyl bromide, or methyl-allyl bromide furnished methyl 8-[5-hexyl-3-allyl-furan-2-yl]-octanoate (1, 56%) or methyl 8-15-hexyl-3-(2-methyl-allyl)-furan-2-yl]-octanoate (2
Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones.
Jeremie J Miller et al.
Journal of the American Chemical Society, 129(10), 2752-2753 (2007-02-21)
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