蒸汽密度
4.2 (vs air)
等级
purum
方案
≥98.0% (GC)
自燃温度
554 °F
包含
silverwool as stabilizer
expl. lim.
7.3 %
折射率
n20/D 1.469 (lit.)
n20/D 1.469
沸点
70-71 °C (lit.)
mp
−119 °C (lit.)
密度
1.398 g/mL at 25 °C (lit.)
SMILES字符串
BrCC=C
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
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应用
Allyl bromide can be used:
- As a starting material to prepare allylaluminum and allylgallium sesquibromides.
- As a precursor in the synthesis of allyl ketones by reacting with substituted nitriles under Barbier-type reaction conditions.
- As a starting material in the synthesis of 2-allyl-1(E),3(E)-dienyl sulfoxides by reacting with 1,2-allenylic sulfoxides using Pd catalyst.
- In the indium catalyzed addition reactions of N-tert-butylsulfinyl aldimines to yield N-tert-butylsulfinylamine chiral building blocks.
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
30.2 °F - closed cup
闪点(°C)
-1 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides
Takai K and Ikawa Y
Organic Letters, 4(10), 1727-1729 (2002)
Highly regio-and stereoselective PdCl2(MeCN) 2-catalyzed cross coupling of 1, 2-allenylic sulfoxides with allyl bromide
Ma S, et al.
Tetrahedron Letters, 45(17), 3517-3520 (2004)
Indium-mediated diastereoselective addition of allyl bromides to enantiomerically pure N-tert-butylsulfinyl aldimines
Foubelo F and Yus M
Tetrahedron Asymmetry, 15(24), 3823-3825 (2004)
Synthesis of allyl ketone via Lewis acid promoted Barbier-type reaction
Lee Adam S-Y and Lin L-S
Tetrahedron Letters, 41(45), 8803-8806 (2000)
Marcel S F Lie Ken Jie et al.
Lipids, 38(12), 1293-1297 (2004-02-12)
A methylene-interrupted C18 keto-acetylenic fatty ester (methyl 12-oxo-9-octadecynoate) was obtained from methyl ricinoleate by bromination-dehydrobromination followed by oxidation. Reaction of methyl 12-oxo-9-octadecynoate with bis(benzonitrile) palladium(II) chloride, allyl bromide, or methyl-allyl bromide furnished methyl 8-[5-hexyl-3-allyl-furan-2-yl]-octanoate (1, 56%) or methyl 8-15-hexyl-3-(2-methyl-allyl)-furan-2-yl]-octanoate (2
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