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Merck
CN

06013

苯基锂 溶液

~1.9 M in dibutyl ether

别名:

PhLi

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关于此项目

经验公式(希尔记法):
C6H5Li
化学文摘社编号:
分子量:
84.04
PubChem Substance ID:
UNSPSC Code:
12352103
Beilstein/REAXYS Number:
506502
MDL number:
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concentration

~1.9 M in dibutyl ether

density

0.835 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

[Li]c1ccccc1

InChI

1S/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;

InChI key

NHKJPPKXDNZFBJ-UHFFFAOYSA-N



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signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

77.0 °F - closed cup

flash_point_c

25 °C - closed cup

法规信息

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分析证书(COA)

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Luka A Wright et al.
Dalton transactions (Cambridge, England : 2003), 44(16), 7230-7241 (2015-03-20)
The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and condensation steps from 6-tributylstannyl-2-(2-methyl-1,3-dioxolan-2-yl)pyridine and 2-bromonitrobenzene. The palladium(II) acetate N,N,N-pincer complexes, [{2-(C6H4-2′-NH)-6-(CMe=NAr)C5H3N}Pd(OAc)] (Ar = 4-i-PrC6H4 (1a), 2,6-i-Pr2C6H3 (1b)), can be prepared by



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货号GTIN
278246-5G04061832541013