06546
甲酸甲酯
suitable for UV/Vis spectroscopy, ≥99.0% (GC)
别名:
蚁酸甲酯
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线性分子式:
HCO2CH3
化学文摘社编号:
分子量:
60.05
EC Number:
203-481-7
UNSPSC Code:
12190000
MDL number:
Beilstein/REAXYS Number:
1734623
vapor density
2.1 (vs air)
assay
≥99.0% (GC)
autoignition temp.
842 °F
expl. lim.
23 %
technique(s)
UV/Vis spectroscopy: suitable
refractive index
n20/D 1.343 (lit.)
bp
32-34 °C (lit.)
mp
−100 °C (lit.)
density
0.974 g/mL at 20 °C (lit.)
λ
1 cm path, H2O reference
UV absorption
λ: 260 nm Amax: 1.000, λ: 265 nm Amax: 0.100, λ: 270 nm Amax: 0.020, λ: 310 nm Amax: 0.010
SMILES string
[H]C(=O)OC
InChI
1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI key
TZIHFWKZFHZASV-UHFFFAOYSA-N
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-2.2 °F - closed cup
flash_point_c
-19 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
John F Marlier et al.
The Journal of organic chemistry, 70(5), 1737-1744 (2005-02-26)
Multiple isotope effects have been measured for the acid-catalyzed hydrolysis of methyl formate in 0.5 M HCl at 20 degrees C. The isotope effects in the present investigation include the carbonyl carbon (13k = 1.028 +/- 0.001), the carbonyl oxygen
D Cain et al.
The Journal of organic chemistry, 66(18), 6092-6095 (2001-09-01)
Free-energy barriers of 9.85 and 11.91 +/- 0.15 kcal/mol at -70.8 degrees C were found by dynamic NMR spectroscopy for the E-to-Z and Z-to-E conversions, respectively, of methyl formate (1) enriched in 13C to 99% for the carbonyl carbon [methyl
T Sethre et al.
International archives of occupational and environmental health, 73(6), 401-409 (2000-09-28)
The aim of the study was to investigate the acute effects of experimental methylformate exposure on the nervous system. In an exposure chamber, 20 subjects were exposed to methylformate at 100 ppm [Swiss maximum allowable concentration (MAC)] for 8 h.
Hiroya Yurimoto et al.
Yeast (Chichester, England), 21(4), 341-350 (2004-03-26)
Methyl formate synthesis during growth on methanol by methylotrophic yeasts has been considered to play a role in formaldehyde detoxification. An enzyme that catalyses methyl formate synthesis was purified from methylotrophic yeasts, and was suggested to belong to a family
Alexandre Faure et al.
The Journal of chemical physics, 135(2), 024301-024301 (2011-07-20)
A potential energy surface for helium interacting with methyl formate has been computed using high-level electronic structure methods. The interaction energies obtained on a three-dimensional grid have been fitted by an analytic function of interatomic distances with correct asymptotic behavior
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| D7750-1G | 04061826690611 |
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