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Merck
CN

09120

2-氨基苯酚

purum, ≥98.0% (HPLC)

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线性分子式:
H2NC6H4OH
化学文摘社编号:
分子量:
109.13
EC Number:
202-431-1
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
606075
MDL number:
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InChI key

CDAWCLOXVUBKRW-UHFFFAOYSA-N

InChI

1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2

SMILES string

Nc1ccccc1O

grade

purum

assay

≥98.0% (HPLC)

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pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Muta. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 2

flash_point_f

334.4 °F - closed cup

flash_point_c

168 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Yoshinori Endo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(43), 13609-13613 (2012-09-13)
Aerobic oxidation: in a biomimetic approach, a mixture of redox catalysts forms couples that effect the aerobic oxidation of a mixture of benzylamine and 2-aminophenol derivatives to give the corresponding benzoxazoles. This biomimetic oxidation proceeds smoothly under mild conditions and
Naganjaneyulu Bodipati et al.
Organic & biomolecular chemistry, 10(10), 1958-1961 (2012-01-31)
Highly reactive o-benzoquinone monoimines were chemically generated and successfully trapped with electron-rich olefins that led to the synthesis of hitherto unknown 1,4-benzoxazine derivatives. This unprecedented transformation was achieved by the oxidation of o-aminophenols bearing appropriate functionality on the arene residue
Michael M Bittner et al.
Journal of the American Chemical Society, 134(12), 5460-5463 (2012-03-16)
The oxidative ring cleavage of aromatic substrates by nonheme Fe dioxygenases is thought to involve formation of a ferrous-(substrate radical) intermediate. Here we describe the synthesis of the trigonal-bipyramdial complex Fe((Ph2)Tp)(ISQ(tBu)) (2), the first synthetic example of an iron(II) center
Ericsson D Coy et al.
Organic letters, 12(9), 1976-1979 (2010-03-27)
An efficient and facile synthesis of trans-dihydrobenzofurans has been accomplished from o-aminophenols and phenylpropenes via a novel (one-pot) diastereoselective Pd-catalyzed oxyarylation reaction. The development and optimization of this method is described.
Bibhesh K Singh et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(3-4), 376-383 (2010-04-27)
A new Schiff base 2-aminophenol-pyrrole-2-carboxaldehyde and its Zn(II), Cd(II), Sn(II) and Pb(II) complexes have been synthesized and characterized by various physicochemical studies. Spectral studies (IR and (1)H NMR) indicate deprotonation and coordination of phenolic oxygen along with binding of pyrrole

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