11626
偶氮二甲酸二异丙酯
technical, ≥94% (GC)
别名:
DIAD, 偶氮二甲酸二异丙酯
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关于此项目
线性分子式:
(CH3)2CHOOCN=NCOOCH(CH3)2
化学文摘社编号:
分子量:
202.21
EC Number:
219-502-8
UNSPSC Code:
12352000
PubChem Substance ID:
Beilstein/REAXYS Number:
1912326
MDL number:
grade
technical
assay
≥94% (GC)
refractive index
n20/D 1.420
bp
75 °C/0.25 mmHg (lit.)
density
1.027 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CC(C)OC(=O)\N=N\C(=O)OC(C)C
InChI
1S/C8H14N2O4/c1-5(2)13-7(11)9-10-8(12)14-6(3)4/h5-6H,1-4H3/b10-9+
InChI key
VVWRJUBEIPHGQF-MDZDMXLPSA-N
Application
作为反应物用于制备：
- 苯并哌喃，类似于传统的大麻素
- 丙型肝炎病毒NS5B聚合酶的MK-3281抑制剂
- 降冰片烯类富含胍聚合物,作为细胞穿透肽（CPP）的模拟物
- 铜绿假单胞菌群体感应分子N-(3-氧化十二烷酰基)-L-同型丝氨酸内酯的类似物,具有免疫抑制作用,但无LasR诱导特性
- 染料敏化太阳能电池的受体-供体-受体有机染料
- 1,3-二恶烷-2-羧酸衍生物，作为PPARα/γ双重激动剂
- 通过Morrison-Brunn-Huisgen甜菜碱的Mitsunobu和Arbuzov型多组分反应制备肼基膦酸盐和肼基二膦酸盐
Other Notes
用于 Mitsunobu 反应的试剂，综述
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O. Mitsunobu
Synthesis, 1-1 (1981)
D.L. Hughes
Org. React., 42, 335-335 (1992)
W Neumann et al.
Dalton transactions (Cambridge, England : 2003), 44(4), 1748-1753 (2014-12-04)
Carbaboranes are increasingly used as pharmacophores to replace phenyl substituents in established drug molecules. In contrast to traditional organic chemistry, elaborate procedures to introduce functionality frequently fail in the case of carbaboranes and their chemistry is often hampered by degradation
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