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Merck
CN

11650

甘菊蓝

standard for GC, ≥99.0% (GC)

别名:

奥甘菊环

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关于此项目

经验公式(希尔记法):
C10H8
化学文摘社编号:
分子量:
128.17
EC Number:
205-993-6
UNSPSC Code:
41116107
PubChem Substance ID:
Beilstein/REAXYS Number:
969517
MDL number:
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InChI key

CUFNKYGDVFVPHO-UHFFFAOYSA-N

InChI

1S/C10H8/c1-2-5-9-7-4-8-10(9)6-3-1/h1-8H

SMILES string

c1ccc2cccc2cc1

assay

≥99.0% (GC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

bp

242 °C (lit.)

mp

98-100 °C (lit.)

application(s)

environmental

format

neat

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Preparation Note

λmax. 270 nm, log ε 4.72 in heptane

pictograms

Environment

hcodes

Hazard Classifications

Aquatic Chronic 2

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A F M Mustafizur Rahman et al.
Chemical communications (Cambridge, England), (10)(10), 1196-1198 (2008-03-01)
In spite of having small pi-conjugation systems, azulenes show large binding constants (10(4)-10(5)) to C(60) and C(70), which are larger than those of monoporphyrins and alternant aromatic hydrocarbons.
Stefan Löber et al.
ChemMedChem, 4(3), 325-328 (2009-02-03)
Blue makes it happen: The non-uniform charge distribution of the blue colored azulene framework is highly suitable for the bioisosteric replacement of bicyclic heteroarene moieties. Showing an analogous binding mode as heterocyclic dopamine D4 receptor-selective lead compounds, the induction of
Atsuya Muranaka et al.
Journal of the American Chemical Society, 132(23), 7844-7845 (2010-05-27)
Azulenocyanine, having four azulene units fused to a tetraazaporphyrin skeleton, is a structural isomer of naphthalocyanine. We synthesized the first example of an azulenocyanine from 1,3-di-tert-butyl-5,6-dicyanoazulene. The macrocycle exhibits broad absorption over the visible and near-IR regions far beyond 1000
Timothy D Lash et al.
The Journal of organic chemistry, 77(5), 2368-2381 (2012-02-01)
A "2 + 2" strategy for synthesizing adj-dicarbaporphyrinoid systems has been developed. In a model study, an azulenylmethylpyrrole dialdehyde was condensed with a dipyrrylmethane in the presence of HCl, followed by oxidation with ferric chloride, to give a modest yield
Ze-Yun Xiao et al.
Organic & biomolecular chemistry, 7(12), 2540-2547 (2009-06-09)
In this paper we report the synthesis and self-assembling behavior of new porphyrin-azulene-porphyrin and porphyrin-azulene conjugates. The porphyrin-azulene-porphyrin conjugate gelates a number of organic solvents, while the porphyrin-azulene conjugates form vesicles in a chloroform-methanol binary mixture. The structures of the

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