12309
p-苯醌
for spectrophotometric det. of amines, ≥99.5% (HPLC)
别名:
醌
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关于此项目
线性分子式:
C6H4(=O)2
化学文摘社编号:
分子量:
108.09
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-405-2
Beilstein/REAXYS Number:
773967
MDL number:
InChI key
AZQWKYJCGOJGHM-UHFFFAOYSA-N
InChI
1S/C6H4O2/c7-5-1-2-6(8)4-3-5/h1-4H
SMILES string
O=C1C=CC(=O)C=C1
vapor density
3.73 (vs air)
vapor pressure
0.1 mmHg ( 25 °C)
assay
≥99.5% (HPLC)
form
powder or crystals
autoignition temp.
815 °F
quality
for spectrophotometric det. of amines
technique(s)
UV/Vis spectroscopy: suitable
sublimation residue
≤0.1%
color
, Faint Yellow to Very Dark Yellow to Very Dark Beige and Green-Yellow
mp
112-114 °C, 113-115 °C (lit.)
Quality Level
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Application
以对苯醌和四硫富瓦烯为介体，研究了自组装膜修饰电极制备酶电化学生物传感器的影响参数。可用于氨基酸、洗发水和药物混合物中半胱氨酸和/或羧甲司坦的分光光度测定。它也可作为过氧化物引发聚丙烯交联的有效催化剂。
Other Notes
用于分光光度法检测微量胺的试剂
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Sol. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
170.6 °F - closed cup
flash_point_c
77 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
D A Zaia et al.
Talanta, 50(5), 1003-1010 (2008-10-31)
A simple, sensitive, and selective method has been developed for determination of cysteine (Cys) or carbocysteine (carboCys) in pharmaceutical products, shampoos and a mixture of amino acids. The results showed the reaction between p-benzoquinone (PBQ) and Cys occurs through the
Peroxide-initiated crosslinking of polypropylene in the presence of p-benzoquinone.
Chodak I and Lazar M.
Journal of Polymer Science: Part A, General Papers, 32 (6), 5432-5437 (1986)
Preparation, characterization and application of alkanethiol self-assembled monolayers modified with tetrathiafulvalene and glucose oxidase at a gold disk electrode.
Campuzano S
Journal of Electroanalytical Chemistry, 526 (1), 92-100 (2002)
Spectrophotometric microdetermination of amines and sulfamates with 1,4-Benzoquinone.
G A Benson et al.
Analytical chemistry, 48(14), 2149-2152 (1976-12-01)
Takafumi Hasegawa et al.
Journal of neurochemistry, 87(2), 470-475 (2003-09-27)
Oxidized metabolites of dopamine, known as dopamine quinone derivatives, are thought to play a pivotal role in the degeneration of dopaminergic neurons. Although such quinone derivatives are usually produced via the autoxidation of catecholamines, tyrosinase, which is a key enzyme
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