14453
2,2′-联吡啶
≥98.0% (NT)
别名:
2,2′-二吡啶基, 2,2′-二吡啶, A,A′-联吡啶
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关于此项目
经验公式（希尔记法）:
C10H8N2
化学文摘社编号:
分子量:
156.18
EC Number:
206-674-4
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
113089
MDL number:
assay
≥98.0% (NT)
bp
273 °C (lit.)
mp
70-73 °C (lit.), ~70 °C
application(s)
vitamins, nutraceuticals, and natural products
SMILES string
c1ccc(nc1)-c2ccccn2
InChI
1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H
InChI key
ROFVEXUMMXZLPA-UHFFFAOYSA-N
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General description
2,2′-Bipyridyl is a symmetrical bipyridine commonly used as a neutral ligand for the complexation with metal ions. The molecule is planar with trans-conformation and crystallizes in the monoclinic crystal system.
Application
2,2′-Bipyridyl has been used in the preparation of:
- Polyvinylchloride with thioxanthone moieties, which can be employed as photoinitiator in photopolymerization.
- A novel block polymer that can form polymeric micelles for drug delivery.
- As a ligand to prepare cyclometalated iridium(III) complexes.
Biochem/physiol Actions
金属蛋白酶抑制剂，铁的高亲和力螯合剂;在10−8 M浓度下可以抑制含Fe2+的酶。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
267.8 °F - closed cup
flash_point_c
131 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Nuclear magnetic resonance spectra of 2, 2'-bipyridyl.
Castellano S, et al.
The Journal of Physical Chemistry, 69(12), 4166-4176 (1965)
1002. The stability of metal complexes of 1, 10-phenanthroline and its analogues. Part I. 1, 10-Phenanthroline and 2, 2'-bipyridyl.
Irving HMNH and Mellor DH.
Journal of the Chemical Society, 5222-5237 (1962)
Cyclometalated Iridium (III) Complexes as Photosensitizers for Long-Range Electron Transfer: Occurrence of a Coulomb Barrier.
Hanss D, et al.
European Journal of Inorganic Chemistry, 2009(32), 4850-4859 (2009)
Novel polymeric micelles for drug delivery: Material characterization and formulation screening.
Janas C, et al.
International Journal of Pharmaceutics, 509(1-2) (2016)
Synthesis and characterization of poly (vinylchloride) type macrophotoinitiator comprising side-chain thioxanthone via click chemistry.
Akat H and Ozkan M
Express Polymer Letters, 5(4), 318-326 (2011)
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