InChI key
XDTMQSROBMDMFD-UHFFFAOYSA-N
InChI
1S/C6H12/c1-2-4-6-5-3-1/h1-6H2
SMILES string
C1CCCCC1
vapor density
2.9 (vs air)
vapor pressure
168.8 mmHg ( 37.7 °C), 77 mmHg ( 20 °C)
grade
puriss.
assay
≥99.5% (GC)
autoignition temp.
500 °F
expl. lim.
9 %
impurities
≤0.0015% non-volatile matter, ≤0.02% water (Karl Fischer)
mp
4-7 °C (lit.)
density
0.779 g/mL at 25 °C (lit.)
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General description
Cyclohexane participates as starting reagent in the photonitrosylation process (PNC process) and affords ε-caprolactam. Its oxidation by employing various oxidants such as hydrogen peroxide, tert-butyl hydroperoxide and molecular oxygen has been reported.
Application
Cyclohexane has been used to prepare the 1.3M solution of sec-butyllithium. It may be used as starting reagent for the synthesis of adipic acid.
Other Notes
A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.
Pertains only in Germany: unversteuert
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Cyclohexane oxidation continues to be a challenge.
Schuchardt ULF, et al.
Applied Catalysis A: General, 211(1), 1-17 (2001)
Hyperbranched nanomolecules: Regular polystyrene dendrigrafts.
Muchtar Z, et al.
Macromolecules, 34(22), 7595-7600 (2001)
Eagleson M.
Concise Encyclopedia Chemistry, 168-168 (1994)
Amanda L Pitts et al.
Journal of the American Chemical Society, 136(24), 8614-8625 (2014-05-16)
Carbon-hydrogen bond activation reactions of four cycloalkanes (C5H10, C6H12, C7H14, and C8H16) by the Cp'Rh(CO) fragments (Cp' = η(5)-C5H5 (Cp) or η(5)-C5Me5 (Cp*)) were modeled theoretically by combining density functional and coupled cluster theories, and their reaction rates were measured
Robert Duran et al.
Environmental science and pollution research international, 22(20), 15215-15229 (2015-02-26)
The exploration of marine Actinobacteria has as major challenge to answer basic questions of microbial ecology that, in turn, will provide useful information to exploit Actinobacteria metabolisms in biotechnological processes. The ecological functions performed by Actinobacteria in marine sediments are
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