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Merck
CN

15706

三氯化硼

purum, ≥99.9%

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经验公式(希尔记法):
BCl3
化学文摘社编号:
分子量:
117.17
EC Number:
233-658-4
UNSPSC Code:
12352106
MDL number:
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vapor density

4.05 (vs air)

vapor pressure

1128 mmHg ( 20 °C), 2815 mmHg ( 55 °C)

grade

purum

assay

≥99.9%

impurities

≤0.05% COCl2, 0.05% Cl2

bp

12.5 °C (lit.)

mp

−107 °C (lit.)

SMILES string

ClB(Cl)Cl

InChI

1S/BCl3/c2-1(3)4

InChI key

FAQYAMRNWDIXMY-UHFFFAOYSA-N

Packaging

罐装,净重 ~5kg

Other Notes

可能实行销售限制

pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Press. Gas Compr. Gas - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

2A - Gases

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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C Matthäus et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57(3), 521-534 (2001-04-13)
A method for expressing quantitatively the vibrational normal modes of a molecule in a basis set consisting of the normal vibrations (plus translations and rotations) of its constituent fragments is presented. The method is illustrated by describing the vibrational modes
Guillaume Reinisch et al.
The journal of physical chemistry. A, 115(18), 4786-4797 (2011-04-16)
We report on a theoretical study of the gas-phase decomposition of boron trichloride in the presence of hydrogen radicals using ab initio energetic calculations coupled to TST, RRKM, and VTST-VRC kinetic calculations. In particular, we present an addition-elimination mechanism (BCl(3)
Dean Marković et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(20), 5969-5975 (2010-04-17)
The first ene reactions of SO(2) and unfunctionalized alkenes are reported. Calculations suggest that the endergonic ene reactions of SO(2) with alkenes can be used to generate beta,gamma-unsaturated sulfinyl and sulfonyl compounds. Indeed, in the presence of one equivalent of
Warwick J Belcher et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 1602-1614 (2008-03-13)
The reactions of boron halides with free base porphyrins under conditions where partial hydrolysis of the boron halides can occur give diboron porphyrin complexes containing BOB moieties in which each boron is bonded to two porphyrin nitrogen atoms. BF(3).OEt(2) with
Robert Winker et al.
International archives of occupational and environmental health, 81(4), 423-428 (2007-07-27)
To examine whether semiconductor workers exposed to complex mixtures of chemical waste show an increase in genotoxic effects, and, if so, whether occupational safety measures protect these workers. To assess chemical exposure in the workplace, air monitoring of boron trifluoride

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