161993
p-甲苯磺酸 一水合物
reagent grade, 98%
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线性分子式:
CH3C6H4SO3H · H2O
化学文摘社编号:
分子量:
190.22
EC Number:
203-180-0
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
3568023
MDL number:
InChI key
KJIFKLIQANRMOU-UHFFFAOYSA-N
InChI
1S/C7H8O3S.H2O/c1-6-2-4-7(5-3-6)11(8,9)10;/h2-5H,1H3,(H,8,9,10);1H2
SMILES string
[H]O[H].Cc1ccc(cc1)S(O)(=O)=O
grade
reagent grade
vapor density
5.9 (vs air)
assay
98%
mp
103-106 °C (lit.)
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Other Notes
This product has been replaced by T35920-Sigma-Aldrich | p-Toluenesulfonic acid monohydrate, ReagentPlus®, 98.5% | CH3C6H4SO3H
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Solvent-Free Reductive Amination: An Organic Chemistry Experiment.
Goldstein SW and Cross AV.
Journal of Chemical Education (2015)
Makoto Ueno et al.
The Journal of organic chemistry, 68(16), 6424-6426 (2003-08-05)
alpha-Tosyloxyketones and alpha-tosyloxyaldehydes were directly prepared from alcohols by treatment with iodosylbenzene and p-toluenesulfonic acid monohydrate in good yields. This method can be used for the direct preparation of thiazoles, imidazoles, and imidazo[1,2-a]pyridines from alcohols in good to moderate yields
Detailed characterization of p-toluenesulfonic acid monohydrate as a convenient, recoverable, safe, and selective catalyst for alkylation of the aromatic nucleus.
Mahindaratne MPD and Wimalasena K.
The Journal of Organic Chemistry, 63(9), 2858-2866 (1998)
The crystal and molecular structure of 4-methyl sulfonic acid (p-toluenesulfonic acid) monohydrate, C7H8SO3-. H3O+, an oxonium salt.
Arora SK and Sundaralingam M.
Acta Crystallographica Section B, Structural Science, 27(7), 1293-1298 (1971)
Abdullah S Al-Bogami et al.
Ultrasonics sonochemistry, 20(5), 1194-1202 (2013-04-18)
The present paper deal with the multi-component condensation of 8-hydroxy quinoline, aromatic aldehydes, and sulfone derivatives catalyzed by p-toluenesulfonic acid for the synthesis of a series of 4H-pyrano[3,2-h]quinoline derivatives in ethanol under ultrasonic irradiations. We provide a series of quinoline
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