16500
4-溴-1-丁烯
purum, ≥98.0% (GC)
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线性分子式:
BrCH2CH2CH=CH2
化学文摘社编号:
分子量:
135.00
EC Number:
225-937-4
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1098377
MDL number:
grade
purum
assay
≥98.0% (GC)
contains
silver wool as stabilizer
refractive index
n20/D 1.462
bp
98-100 °C (lit.)
density
1.33 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
BrCCC=C
InChI
1S/C4H7Br/c1-2-3-4-5/h2H,1,3-4H2
InChI key
DMAYBPBPEUFIHJ-UHFFFAOYSA-N
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General description
Stereoselective epoxidation of 4-bromo-1-butene was carried out with three alkene-utilizing bacteria: Mycobacterium LI, Mycobacterium E3 and Nocardia IP1.
Application
4-Bromo-1-butene was used in the synthesis of 4-(3-butenyloxy)benzoic acid. It was also used in the total synthesis of largazole.
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
33.8 °F - closed cup
flash_point_c
1 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Yongcheng Ying et al.
Journal of the American Chemical Society, 130(26), 8455-8459 (2008-05-30)
Full details of the concise and convergent synthesis (eight steps, 19% overall yield), its extension to the preparation of a series of key analogues, and the molecular target and pharmacophore of largazole are described. Central to the synthesis of largazole
Stereoselective epoxidation of 4-bromo-1-butene and 3-butene-1-ol with three alkene-utilizing bacteria.
Archelas A, et al.
Biocatalysis and Biotransformation, 1(4), 283-292 (1988)
Synthesis and photopolymerization of a liquid-crystalline diepoxide.
Broer DJ, et al.
Macromolecules, 26(6), 1244-1247 (1993)
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