等级
purum
方案
≥98.0% (GC)
折射率
n20/D 1.436 (lit.)
n20/D 1.436
沸点
105-106 °C/767 mmHg (lit.)
密度
1.199 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)CBr
InChI
1S/C5H11Br/c1-5(2,3)4-6/h4H2,1-3H3
InChI key
CQWYAXCOVZKLHY-UHFFFAOYSA-N
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应用
1-Bromo-2,2-dimethylpropane was used in the synthesis of S-alkylated cysteine derivatives with branched alkyl chains. It was used in synthesis of secondary amines from alkyl tosylates or alkyl halides via nucleophilic substitution reaction.
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
44.6 °F - closed cup
闪点(°C)
7 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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An improved method for cysteine alkylation.
Perrey DA and Uckun FM.
Tetrahedron Letters, 42(10), 1859-1861 (2001)
Carmen E Lisowski et al.
The journal of physical chemistry. A, 114(38), 10395-10402 (2010-09-03)
The recombination of chloromethyl and t-butyl radicals at room temperature was used to generate neopentyl chloride molecules with 89 kcal mol(-1) of internal energy. The observed unimolecular reactions, which give 2-methyl-2-butene and 2-methyl-1-butene plus HCl, as products, are explained by
J Ashby et al.
Mutation research, 140(2-3), 71-74 (1984-06-01)
Neopentyl bromide and pentaerythrityl tetrachloride were shown here to be non-mutagenic to 7 strains of Salmonella typhimurium. These inactivities are reflected in the inability of either compound to produce a colour reaction in the chemical alkylation test of Epstein (4-nitrobenzylpyridine
Direct mono-N-alkylation of amines in ionic liquids: chemoselectivity and reactivity.
Chiappe C and Pieraccini D.
Green Chemistry, 5(2), 193-197 (2003)
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