17281
五氟丙酰咪唑
derivatization grade (GC derivatization), ≥98.5%
别名:
1-(全氟丙酰)咪唑
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关于此项目
经验公式（希尔记法）:
C6H3F5N2O
化学文摘社编号:
分子量:
214.09
EC 号:
MDL编号:
UNSPSC代码:
41116105
PubChem化学物质编号:
NACRES:
NA.22
等级
derivatization grade (GC derivatization)
质量水平
方案
≥98.5% (GC)
≥98.5%
反应适用性
reagent type: derivatization reagent
reaction type: Esterifications
技术
GC/MS: suitable
折射率
n20/D 1.399
密度
1.4 g/mL at 20 °C (lit.)
储存温度
−20°C
SMILES字符串
FC(F)(F)C(F)(F)C(=O)n1ccnc1
InChI
1S/C6H3F5N2O/c7-5(8,6(9,10)11)4(14)13-2-1-12-3-13/h1-3H
InChI key
VZUSRIIEPFQBNE-UHFFFAOYSA-N
一般描述
Derivatization before a GC analysis helps in yielding distinctive products, which can be achieved using a derivatizing reagent that reacts with amino and hydroxyl functionalities quantitatively. 1-(Pentafluoropropionyl)imidazole (PFPI) is a derivatizing reagent which was found to give high yield of products than pentafluoropropionic anhydride during preparation of methyl ester/pentafluoropropionyl derivatives.
应用
PFPI may be used to incubate the lyophilized samples, for derivatization during GC/MS analysis to measure total d-chiro-Inositol content absorbed by rodents.
其他说明
气相色谱中醇和羧酸等物质的衍生化试剂
Reagent for methyl ester, pentafluoropropionyl.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
F Karoum et al.
British journal of pharmacology, 56(4), 403-411 (1976-04-01)
1 Mass fragmentography was used to measure whole brain concentrations of some of the major metabolites of tyramine, octopamine, dopamine and noradrenaline in acutely treated and in ethanol-dependent rats. 2 Treatments with ethanol, either acutely or chronically, failed to alter
F. Karoum et al.
Biomedical Mass Spectrometry, 2, 183-183 (1975)
J.T. Etse et al.
Journal of Natural Products, 51, 314-314 (1988)
Xiaobo Lin et al.
The British journal of nutrition, 102(10), 1426-1434 (2009-07-10)
d-chiro-inositol (DCI) and pinitol (1d-3-O-methyl-chiro-inositol) are distinctive inositols reported to possess insulin-mimetic properties. DCI-containing compounds are abundant in common laboratory animal feed. By GC-MS of 6 m-HCl hydrolysates, Purina Laboratory Rodent Diet 5001 (diet 5001) contained 0.23 % total DCI
D.R. Knapp
Handbook of Analytical Derivatization Reactions, 208-208 (1979)
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