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Merck
CN

17878

Sigma-Aldrich

溴仿

puriss., ≥99.0% (GC)

别名:

三溴甲烷

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关于此项目

经验公式(希尔记法):
CHBr3
化学文摘社编号:
分子量:
252.73
Beilstein:
1731048
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
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蒸汽密度

8.7 (vs air)

蒸汽压

5 mmHg ( 20 °C)

等级

puriss.

方案

≥99.0% (GC)

包含

~0.05% amylene as stabilizer

折射率

n20/D 1.595 (lit.)
n20/D 1.596

沸点

146-150 °C (lit.)

mp

5-8 °C (lit.)

溶解性

H2O: soluble
acetone: miscible
alcohol: miscible
benzene: miscible
chloroform: miscible
diethyl ether: miscible

密度

2.89 g/mL at 25 °C (lit.)

SMILES字符串

BrC(Br)Br

InChI

1S/CHBr3/c2-1(3)4/h1H

InChI key

DIKBFYAXUHHXCS-UHFFFAOYSA-N

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一般描述

Polar ordering induced by pressure in bromoform has been determined using single-crystal X-ray diffraction.

应用

Bromoform was used to carry out the risk assessment of tribromomethane in drinking water.

警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

106.3 °F - closed cup - (own results)

闪点(°C)

41.3 °C - closed cup - (own results)

法规信息

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分析证书(COA)

Lot/Batch Number

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Kamil F Dziubek et al.
The journal of physical chemistry. B, 112(38), 12001-12009 (2008-08-02)
Polar ordering has been induced by pressure in solid chloroform (trichloromethane), CHCl3, and bromoform (tribromomethane), CHBr3, obtained by isochoric and isothermal freezing in a diamond anvil cell. Structures of these new polymorphs have been determined by single-crystal X-ray diffraction, CHCl3
Nasrul Hamidin et al.
Water research, 42(13), 3263-3274 (2008-06-03)
The presence of chlorinated disinfection by-products (DBPs) in drinking water is a public health issue, due to their possible adverse health effects on humans. To gauge the risk of chlorinated DBPs on human health, a risk assessment of chloroform (trichloromethane
Lisa George et al.
The Journal of chemical physics, 135(12), 124503-124503 (2011-10-07)
Iso-polyhalomethanes are known reactive intermediates that play a pivotal role in the photochemistry of halomethanes in condensed phases. In this work, iso-bromoform (iso-CHBr(3)) and its deuterated isotopomer were characterized by matrix isolation infrared and UV/visible spectroscopy, supported by ab initio
Bichismita Sahu et al.
The Journal of organic chemistry, 74(6), 2601-2604 (2009-02-26)
Addition of bromoform to conjugated nitroalkenes in the presence of Mg provided beta-tribromomethyl nitroalkanes in good to excellent yields and diastereoselectivity. These novel Michael adducts, formed under radical conditions, underwent elimination of HBr in the same pot under reflux to
M Valcke et al.
Regulatory toxicology and pharmacology : RTP, 59(2), 258-269 (2010-10-26)
The objective of this study was to assess the impact of the exposure route on the human kinetic adjustment factor (HKAF), for which a default value of 3.16 is used in non-cancer risk assessment. A multi-route PBPK model was modified

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