18490
3-溴甲苯
purum, ≥98.0% (GC)
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线性分子式:
CH3C6H4Br
化学文摘社编号:
分子量:
171.03
EC Number:
209-702-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1903633
MDL number:
grade
purum
assay
≥98.0% (GC)
refractive index
n20/D 1.552 (lit.), n20/D 1.553
bp
183.7 °C (lit.)
mp
−40 °C (lit.)
density
1.41 g/mL at 25 °C (lit.)
SMILES string
Cc1cccc(Br)c1
InChI
1S/C7H7Br/c1-6-3-2-4-7(8)5-6/h2-5H,1H3
InChI key
WJIFKOVZNJTSGO-UHFFFAOYSA-N
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General description
3-Bromotoluene undergoes palladium-catalyzed cyanation using K4[Fe(CN)6] as the cyanide surrogate. It undergoes palladium-catalysed reaction with alkynyltriarylborates to yield trisubstituted alkenylboranes.
Application
3-Bromotoluene was used in precise determination of bromine isotope ratio in organic compounds by MC-ICPMS.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
140.0 °F
flash_point_c
60 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
High precision determination of bromine isotope ratio by GC-MC-ICPMS.
Gelman F and Halicz L.
International Journal of Mass Spectrometry, 289(2), 167-169 (2010)
Naoki Ishida et al.
Chemical communications (Cambridge, England), (42)(42), 4381-4383 (2007-10-25)
The palladium-catalysed reaction of alkynyltriarylborates with aryl halides afforded trisubstituted alkenylboranes, in which two different aryl groups were installed across the carbon-carbon double bond in a cis arrangement.
Efficient cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by a palladium-indolylphosphine complex.
Yeung PY, et al.
Tetrahedron Letters, 52(52), 7038-7041 (2011)
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