19170
3-丁烯-1-醇
purum, ≥98.0% (GC)
别名:
烯丙基甲醇
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关于此项目
线性分子式:
CH2=CHCH2CH2OH
化学文摘社编号:
分子量:
72.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-991-3
Beilstein/REAXYS Number:
1633504
MDL number:
产品名称
3-丁烯-1-醇, purum, ≥98.0% (GC)
InChI key
ZSPTYLOMNJNZNG-UHFFFAOYSA-N
InChI
1S/C4H8O/c1-2-3-4-5/h2,5H,1,3-4H2
SMILES string
OCCC=C
grade
purum
assay
≥98.0% (GC)
refractive index
n20/D 1.421 (lit.)
n20/D 1.422
bp
112-114 °C (lit.)
density
0.838 g/mL at 25 °C (lit.)
functional group
allyl
hydroxyl
Quality Level
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Application
3-Buten-1-ol was used as a starting reagent in asymmetric total synthesis of natural seimatopolide B. It was also used in the synthesis of catalytic bimetallic nanoparticles.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
91.4 °F - closed cup
flash_point_c
33 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Biologically programmed synthesis of bimetallic nanostructures.
Slocik JM and Naik RR.
Advanced Materials, 18(15), 1988-1992 (2006)
Alternating copolymers of functional alkenes with carbon monoxide.
Kacker S, et al.
Macromolecules, 29(18), 5852-5858 (1996)
Chada Raji Reddy et al.
Organic & biomolecular chemistry, 11(20), 3355-3364 (2013-04-09)
The asymmetric total synthesis of natural seimatopolide B along with its enantiomer is described starting from readily available 5-hexen-1-ol and 3-buten-1-ol. The key steps involved are Jacobson hydrolytic kinetic resolution, proline-catalyzed α-hydroxylation, Yamaguchi esterification and ring-closing metathesis. This asymmetric total
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