20025
2-叔丁基亚氨基-2-二乙基氨基-1,3-二甲基全氢-1,3,2-二氮杂磷
purum, ≥98.0% (GC)
别名:
BEMP
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关于此项目
经验公式（希尔记法）:
C13H31N4P
化学文摘社编号:
分子量:
274.39
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5534901
Assay:
≥98.0% (GC)
Form:
liquid
InChI
1S/C13H31N4P/c1-8-17(9-2)18(14-13(3,4)5)15(6)11-10-12-16(18)7/h8-12H2,1-7H3
SMILES string
CCN(CC)P1(=NC(C)(C)C)N(C)CCCN1C
InChI key
VSCBATMPTLKTOV-UHFFFAOYSA-N
grade
purum
assay
≥98.0% (GC)
form
liquid
refractive index
n20/D 1.477 (lit.), n20/D 1.477
bp
74 °C/0.03 mmHg (lit.)
density
0.948 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
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Application
2- 叔 -丁亚胺-2-二乙氨基-1,3-二甲基二氢-1,3,2-二氮杂膦 (BEMP)，有机磷碱可用于以下研究：
- 2,3-二氢苯并 [1,4] 二氧杂萘-5-酮的合成。
- 作为碳酸烷基化反应的催化剂。
- 作为六元环碳酸盐可控“永生”开环聚合 (iROP) 中的有机催化剂。
General description
2- 叔 -丁亚胺-2-二乙氨基-1，3-二甲基二氢-1，3，2-二氮杂膦 (BEMP) 是一种磷腈碱。BEMP 参与温和的碱催化 N -磺酰基氮杂环丙烷的亲核开环。以聚苯乙烯为载体的 BEMP (PS-BEMP) 是一种高效的酚醛开环催化剂。BEMP 比 DBU（l,8-二氮杂双环 [5.4.0] 十一烯）的碱性强 2000 倍，空间位阻也大很多。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Marion Helou et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(46), 13805-13813 (2010-10-15)
Six-membered cyclic carbonates, namely trimethylene carbonate (TMC), 3,3-dimethoxytrimethylene carbonate (DMTMC) and 3-benzyloxytrimethylene carbonate (BTMC), undergo controlled "immortal" ring-opening polymerization (iROP) under mild conditions (bulk, 60-150 °C), by using organocatalysts, including an amine [4-N,N-dimethylaminopyridine (DMAP)], a guanidine [1,5,7-triazabicyclo-[4.4.0]dec-5-ene (TBD)], or a
Thomas A Moss et al.
Chemical communications (Cambridge, England), (21)(21), 2474-2476 (2008-05-21)
N-Mesitylene sulfonyl and N-tosyl aziridines have been identified as effective electrophiles in alkylation reactions of carbon acids catalyzed by the organic phosphorine base BEMP; yields of up to 99% for a range of pro-nucleophiles under mild reaction conditions are reported.
2-tert-Butylimino-2-diethylamino-1, 3-dimethylperhydro-1, 3, 2-diazaphosphorine Supported on Polystyrene (PS-BEMP) as an Efficient Recoverable and Reusable Catalyst for the Phenolysis of Epoxides under Solvent-Free Conditions.
Zvagulis A, et al.
Advanced Synthesis & Catalysis, 352(14-15), 2489-2496 (2010)
Ke Wen et al.
The Journal of organic chemistry, 67(22), 7887-7889 (2002-10-26)
A short and efficient synthesis of 2'-O-methoxyethylguanosine (8) is described. Central to this strategy is the development of a novel silicon-based protecting group (MDPSCl(2), 2) used to protect the 3',5'-hydroxyl groups of the ribose. Silylation of guanosine with 2 proceeded
M.J. O'Donnell et al.
Tetrahedron Letters, 39, 8775-8775 (1998)
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